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[Contents scheme]

Acta Cryst. (2013). E69, o25
[ doi:10.1107/S1600536812049094 ]

Ethyl 8,13-dioxa-21-azapentacyclo[18.5.1.02,7.014,19.021,25]hexacosa-2(7),3,5,14,16,18-hexaene-26-carboxylate

S. Narayanan, T. Srinivasan, S. Purushothaman, R. Raghunathan and D. Velmurugan

Abstract: In the title compound, C26H31NO4, the five-membered rings of the central pyrrolizine system adopt N-envelope conformations. The ethyl acetate group adopts an extended conformation. The dihedral angle between the benzene rings is 36.6 (1)°. In the crystal, C-H...O hydrogen bonds form a zigzag chain running along the b-axis directions. The crystal structure is futher consolidated by C-H...[pi] interactions.


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