Received 20 November 2012
In the title compound, C11H15N3O2S·C2H3N, the dihedral angle between the benzene ring and the mean plane of the hydrazinecarbothioamide group is 75.1 (2)°. In the crystal, the main molecule is linked to the solvent molecule by a weak N-HN hydrogen bond while O-HS hydrogen bonds link the molecules into columns along .
For thiosemicarbazone structures and their biological activity, see: Lobana et al. (2009). For thiosemicarbazone as ligands for hydrogenations or metal-catalysed reactions, see: Pelagatti et al. (1998); Xie et al. (2010). For a related structure, see: Anderson et al. (2012). For standard bond lengths, see: Allen et al. (1987).
Data collection: CrysAlis PRO (Agilent, 2012); cell refinement: CrysAlis PRO; data reduction: CrysAlis RED (Agilent, 2012); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL.
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: RK2388 ).
JPJ acknowledges the NSF-MRI program (grant No. CHE1039027) for funds to purchase the X-ray diffractometer.
Agilent (2012). CrysAlis PRO and CrysAlis RED Agilent Technologies, Yarnton, England.
Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G. & Taylor, R. (1987). J. Chem. Soc. Perkin Trans. 2, pp. S1-19.
Anderson, B. J., Kennedy, C. J. & Jasinski, J. P. (2012). Acta Cryst. E68, o2982.
Lobana, T. S., Sharma, R., Bawa, G. & Khanna, S. (2009). Coord. Chem. Rev. 253, 977-1055.
Pelagatti, P., Venturini, A., Carcelli, M., Costa, M., Bacchi, A., Pelizzi, G. & Pelizza, C. (1998). J. Chem. Soc. Dalton Trans. pp. 2715-2721.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Xie, G., Chellan, P., Mao, J., Chibale, K. & Smith, G. S. (2010). Adv. Synth. Catal. 352, 1641-1647.