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Volume 69 
Part 1 
Pages m43-m44  
January 2013  

Received 29 November 2012
Accepted 6 December 2012
Online 12 December 2012

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Key indicators
Single-crystal X-ray study
T = 150 K
Mean [sigma](N-C) = 0.012 Å
R = 0.047
wR = 0.092
Data-to-parameter ratio = 18.0
Details
Open access

catena-Poly[[tetrakis(hexamethylphosphoramide-[kappa]O)bis(nitrato-[kappa]2O,O')erbium(III)] [silver(I)-di-[mu]-sulfido-tungstate(VI)-di-[mu]-sulfido]]

Hongyang Wei,a Jinfang Zhangb and Chi Zhanga*

aInstitute of Molecular Engineering and Advanced Materials, School of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiaolingwei, Nanjing 210094, Jiangsu, People's Republic of China, and bInstitute of Science and Technology, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, People's Republic of China
Correspondence e-mail: chizhang@mail.njust.edu.cn

In the title compound, {[Er(NO3)2(C6H18N3OP)4][AgWS4]}n, the polymeric anionic chain {[AgWS4]-}n extends along [001]. The ErIII atom in the cation is coordinated by eight O atoms from two bidentate nitrate anions and four hexamethylphosphoramide ligands in a distorted square-antiprismatic geometry. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having a [WS4Ag] repeat unit. The polymeric anionic chain has a distorted linear configuration, with W-Ag-W and Ag-W-Ag angles of 161.37 (2) and 153.548 (12)°, respectively. The title complex is isotypic with the Y, Yb, Eu, Nd, La, Dy, Sm, Lu and Tb analogues.

Related literature

For one-dimensional Mo(W)/S/Ag anionic polymers, see: Niu et al. (2004[Niu, Y. Y., Zheng, H. G., Hou, H. W. & Xin, X. Q. (2004). Coord. Chem. Rev. 248, 169-183.]); Zhang et al. (2010[Zhang, J. F., Meng, S. C., Song, Y. L., Zhao, H. J., Li, J. H., Qu, G. J., Sun, L., Humphrey, M. G. & Zhang, C. (2010). Chem. Eur. J. 16, 13946-13950.]). For their unique properties, see: Zhang, Song et al. (2007[Zhang, C., Song, Y. L. & Wang, X. (2007). Coord. Chem. Rev. 251, 111-141.]). For isotypic compounds, see: Zhang, Cao et al. (2007[Zhang, J.-F., Cao, Y., Qian, J. & Zhang, C. (2007). Acta Cryst. E63, m2248-m2249.]); Cao et al. (2007[Cao, Y., Zhang, J.-F., Qian, J. & Zhang, C. (2007). Acta Cryst. E63, m2076-m2077.]); Zhang, Qian et al. (2007[Zhang, J., Qian, J., Cao, Y. & Zhang, C. (2007). Acta Cryst. E63, m2386-m2387.]); Tang, Zhang & Zhang (2008[Tang, G., Zhang, J. & Zhang, C. (2008). Acta Cryst. E64, m478.]); Tang, Zhang, Zhang & Lu (2008[Tang, G., Zhang, J., Zhang, C. & Lu, L. (2008). Acta Cryst. E64, m399-m400.]); Zhang (2010[Zhang, J. (2010). Acta Cryst. E66, m1479.]); Zhang (2011a[Zhang, J. (2011a). Acta Cryst. E67, m1206-m1207.],b[Zhang, J. (2011b). Acta Cryst. E67, m1365.]); Zhang (2012a[Zhang, J. (2012a). Acta Cryst. E68, m770-m771.],b[Zhang, J. (2012b). Acta Cryst. E68, m843-m844.]).

[Scheme 1]

Experimental

Crystal data

  • [Er(NO3)2(C6H18N3OP)4][AgWS4]

  • Mr = 1428.09

  • Monoclinic, P 21 /c

  • a = 15.763 (3) Å

  • b = 29.579 (6) Å

  • c = 11.368 (2) Å

  • [beta] = 90.83 (3)°

  • V = 5299.8 (17) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 4.43 mm-1

  • T = 150 K

  • 0.2 × 0.17 × 0.15 mm
Data collection

  • Rigaku Saturn724+ diffractometer

  • Absorption correction: multi-scan (CrystalClear; Rigaku, 2008[Rigaku (2008). CrystalClear. Rigaku Corporation, Tokyo, Japan.]) Tmin = 0.428, Tmax = 0.514

  • 26753 measured reflections

  • 9597 independent reflections

  • 8722 reflections with I > 2[sigma](I)

  • Rint = 0.044

  • Standard reflections: 0
Refinement

  • R[F2 > 2[sigma](F2)] = 0.047

  • wR(F2) = 0.092

  • S = 1.08

  • 9597 reflections

  • 532 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.91 e Å-3

  • [Delta][rho]min = -1.04 e Å-3

Data collection: CrystalClear (Rigaku, 2008[Rigaku (2008). CrystalClear. Rigaku Corporation, Tokyo, Japan.]); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: RZ5031 ).

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 50472048) and the Program for New Century Excellent Talents in Universities (NCET-05-0499).

References

Cao, Y., Zhang, J.-F., Qian, J. & Zhang, C. (2007). Acta Cryst. E63, m2076-m2077.  [CSD] [CrossRef] [details]
Niu, Y. Y., Zheng, H. G., Hou, H. W. & Xin, X. Q. (2004). Coord. Chem. Rev. 248, 169-183.  [ISI] [CrossRef] [ChemPort]
Rigaku (2008). CrystalClear. Rigaku Corporation, Tokyo, Japan.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Tang, G., Zhang, J. & Zhang, C. (2008). Acta Cryst. E64, m478.  [CSD] [CrossRef] [details]
Tang, G., Zhang, J., Zhang, C. & Lu, L. (2008). Acta Cryst. E64, m399-m400.  [CSD] [CrossRef] [details]
Zhang, J. (2010). Acta Cryst. E66, m1479.  [CSD] [CrossRef] [details]
Zhang, J. (2011a). Acta Cryst. E67, m1206-m1207.  [CSD] [CrossRef] [details]
Zhang, J. (2011b). Acta Cryst. E67, m1365.  [CSD] [CrossRef] [details]
Zhang, J. (2012a). Acta Cryst. E68, m770-m771.  [CSD] [CrossRef] [details]
Zhang, J. (2012b). Acta Cryst. E68, m843-m844.  [CSD] [CrossRef] [details]
Zhang, J.-F., Cao, Y., Qian, J. & Zhang, C. (2007). Acta Cryst. E63, m2248-m2249.  [CSD] [CrossRef] [details]
Zhang, J. F., Meng, S. C., Song, Y. L., Zhao, H. J., Li, J. H., Qu, G. J., Sun, L., Humphrey, M. G. & Zhang, C. (2010). Chem. Eur. J. 16, 13946-13950.  [CSD] [CrossRef] [ChemPort] [PubMed]
Zhang, J., Qian, J., Cao, Y. & Zhang, C. (2007). Acta Cryst. E63, m2386-m2387.  [CSD] [CrossRef] [details]
Zhang, C., Song, Y. L. & Wang, X. (2007). Coord. Chem. Rev. 251, 111-141.  [ISI] [CrossRef] [ChemPort]

Acta Cryst (2013). E69, m43-m44   [ doi:10.1107/S1600536812049987 ]

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