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Acta Cryst. (2013). E69, m15
[ doi:10.1107/S1600536812047927 ]

[mu]-Azido-[kappa]2N1:N1-[mu]-chlorido-bis[(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-[kappa]2C1,N)palladium(II)] chloroform monosolvate

A. C. Mafud, M. A. R. Oliviera and M. T. P. Gambardella

Abstract: In the binuclear title complex, [Pd2(C11H13ClN)2Cl(N3)]·CHCl3, each PdII atom has a slightly distorted square-planar geometry being coordinated by a C and an N atom of the 2-chloro-3-dimethylamino-1-phenylpropyl ligand, a bridging Cl atom and an N atom of a bridging end-on azide group. There is a short intramolecular C-H...Cl contact in the complex molecule. In the crystal, the chloroform solvent molecule is linked to the complex via a C-H...[pi] interaction.


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