[Open access]

[Contents scheme]

Acta Cryst. (2013). E69, m36
[ doi:10.1107/S1600536812049768 ]

(Benzyl isocyanide-[kappa]C1)chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-[kappa]2C1,N)palladium(II)

A. C. Mafud, M. A. R. Oliviera and M. T. P. Gambardella

Abstract: In the title compound, [Pd(C11H13ClN)Cl(C8H7N)], which crystallized in the chiral space group P212121, the PdII atom is coordinated by two C atoms, a Csp2 atom of the 2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. In the complex, there is a short C-H...Cl hydrogen bond and a C-H...[pi] interaction. In the crystal, molecules are linked via C-H...Cl hydrogen bonds, forming chains along the a-axis direction.

Copyright © International Union of Crystallography
IUCr Webmaster