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Acta Cryst. (2013). E69, m26
[ doi:10.1107/S1600536812049616 ]

Bis(1,10-phenanthroline-[kappa]2N,N')(sulfato-[kappa]2O,O')cobalt(II) propane-1,2-diol monosolvate

K.-L. Zhong

Abstract: In the title compound, [Co(SO4)(C12H8N2)2]·C3H8O2, the CoII atom (site symmetry 2) has a distorted octahedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O'-bidentate sulfate ligand, in which the S atom has site symmetry 2. The dihedral angle between the two chelating N2C2 groups is 84.46 (15)°. The complex and solvent molecules are connected through O-H...O hydrogen bonds. The solvent molecule is equally disordered over two positions and is also located on a twofold axis.


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