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Acta Cryst. (2013). E69, m75-m76
[ doi:10.1107/S1600536812051999 ]

cis-Bis(1,10-phenanthroline-[kappa]2N,N')bis(pyridin-4-amine-[kappa]N1)ruthenium(II) bis(hexafluoridophosphate)

M. R. Camilo, F. T. Martins, V. R. S. Malta, J. Ellena and R. M. Carlos

Abstract: In the title complex, [Ru(C12H8N2)2(C5H6N2)2](PF6)2, the RuII atom is bonded to two [alpha]-diimine ligands, viz. 1,10-phenanthroline (phen), in a cis configuration, in addition with with two 4-aminopyridine (4Apy) ligands, resulting in a distorted octahedral coordination geometry. N-H...F hydrogen-bonding interactions play an important role in the crystal assembly: 21-screw-axis-related complex molecules and PF6- counter-ions alternate in helical chains formed along the a axis by means of these contacts. N-H...[pi] contacts (H...centroid = 3.45 Å) are responsible for cross-linking between the helical chains along [001].


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