Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 2 (February 2013)


inorganic compounds



Acta Cryst. (2013). E69, i6    [ doi:10.1107/S1600536812050945 ]

Schaurteite, Ca3Ge(SO4)2(OH)6·3H2O

M. J. Origlieri and R. T. Downs

Abstract: This report presents the first crystal structure determination of the mineral schaurteite, ideally Ca3Ge(SO4)2(OH)6·3H2O, tricalcium germanium bis(sulfate) hexahydroxide trihydrate. This single-crystal X-ray diffraction study investigated a natural sample from the type locality at Tsumeb, Namibia. Schaurteite is a member of the fleischerite group of minerals, which also includes fleischerite, despujolsite, and mallestigite. The structure of schaurteite consists of slabs of Ca(O,OH,H2O)8 polyhedra (site symmetry mm2) interleaved with a mixed layer of Ge(OH)6 octahedra (-3m.) and SO4 tetrahedra (3m.). There are two H atoms in the asymmetric unit, both located by full-matrix refinement, and both forming O-H...O hydrogen bonds.


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