Received 1 January 2013
aD. Ghitu Institute of Electronic Engineering and Nanotechnologies, 3/3 Academy Street, MD-2028, Chisinau, Republic of Moldova,bDepartment of Biology & Chemistry, New Mexico Highlands University, 803 University Avenue, Las Vegas, NM 87701, USA,cX-Ray Structural Centre, A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Street, B-334, Moscow 119991, Russian Federation, and dInstitute of Applied Physics Academy of Science of Moldova, 5 Academy Street, MD-2028, Chisinau, Republic of Moldova.
Correspondence e-mail: email@example.com
In the title compound, C4H6N4·C3H6O, the pyrimidine-2,4-diamine molecule is nearly planar (r.m.s. deviation = 0.005 Å), with the endocyclic angles covering the range 114.36 (10)-126.31 (10)°. In the crystal, N-HN and N-HO hydrogen bonds link the molecules into ribbons along , and weak C-H interactions consolidate further the crystal packing.
For the biological activity of pyrimidine derivatives, see: Hall et al. (1993); Gengeliczki et al. (2011). For the crystal structures of related compounds, see: Bertolasi et al. (2002); Draguta et al. (2012). For bond lengths in organic compounds, see: Allen et al. (1987). For hydrogen-bonding graph-set notation, see: Bernstein et al. (1995).
Data collection: APEX2 (Bruker, 2005); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: CV5381 ).
The authors are grateful for NSF support via DMR grant 0934212 (PREM) and CHE 0832622.
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