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Figure 2 Octa­hedral geometry at Zn1A (left) and trigonal bipyramidal geometry at Zn1B (right). In-plane bond angles (°) have been indicated. N3—Zn1—N4 undergoes an opening of 27.4° from B to A to accommodate the extra perchlorate ligand O1D. In both complexes the N5—Zn1—N3/N4/O1 angles are slightly larger than the N2—Zn1—N3/N4/O1 angles, with ranges 96.0 − 102.8° and 78.7 − 80.3°, respectively.

ISSN: 2056-9890
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