Acta Cryst. (2013). E69, m117-m118
[ doi:10.1107/S160053681300130X ]

cis-Dichlorido(dimethyl sulfoxide-S)(N,N,N',N'-tetramethylguanidine-N'')platinum(II)

I. I. Eliseev, N. A. Bokach, M. Haukka and I. A. Golenya

Abstract: In the title compound, cis-[PtCl₂(C₅H₁₃N₃)(C₂H₆OS)], the four-coordinate Pt^II atom is bonded to one N atom of the N,N,N',N'-tetramethylguanidine ligand, one dimethyl sulfoxide S atom and two chloride ligands, forming a cis-square-planar geometry. The bond lengths and angles of the N-Pt-Cl functionality are typical for imine dichloridoplatinum(II) complexes. The H atom of the imino group is oriented towards the O atom of the sulfoxide group of a neighboring molecule and forms an N-HO hydrogen bond.

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