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Acta Cryst. (2013). E69, m83-m84
[ doi:10.1107/S1600536812051562 ]

Di-[mu]-thiosemicarbazide-[kappa]4S:S-bis[chloridobis(triphenylphosphane-[kappa]P)silver(I)]

Y. Wattanakanjana, C. Pakawatchai and R. Nimthong

Abstract: The dinuclear title complex, [Ag2Cl2(CH5N3S)2(C18H15P)2], lies across an inversion center. The AgI ion exhibits a slightly distorted tetrahedral coordination geometry formed by a P atom from a triphenylphosphane ligand, two metal-bridging S atoms from thiosemicabazide ligands and one chloride ion. The S atoms bridge two symmetry-related AgI ions, forming a strictly planar Ag2S2 core with an Ag...Ag separation of 2.7802 (7) Å. There is an intramolecular N-H...Cl hydrogen bond. In the crystal, N-H...Cl and N-H...S hydrogen bonds link complex molecules, forming layers parallel to (001). These layers are connected through [pi]-[pi] stacking interactions [centroid-centroid distance = 3.665 (2) Å], leading to the formation of a three-dimensional network.


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