Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 2 (February 2013)


metal-organic compounds



lh5575 scheme

Acta Cryst. (2013). E69, m126    [ doi:10.1107/S1600536813002080 ]

[mu]-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate

A. D. Royappa, J. A. Golen, A. L. Rheingold and A. T. Royappa

Abstract: The dinuclear molecule of the title compound, [Cu2(C2O4)(C18H15P)4]·2CH2Cl2, lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two CuI ions via two pairs of O atoms. Two triphenylphosphine ligands also coordinate each symmetry-related CuI ion, resulting in a distorted tetrahedral geometry [O-Cu-O = 80.57 (5)° and P-Cu-P = 125.72 (2)°]. In the crystal, there are two dichloromethane solvent molecules for each dinuclear complex.


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