Acta Cryst. (2013). E69, m116
[ doi:10.1107/S1600536813001414 ]
Abstract: The asymmetric unit of the title compound, [CuBr2(C6H7N)2], contains one half-molecule, the whole molecule being generated by inversion through a center located at the CuII atom. The geometry around the CuII atom is square planar. Semicoordinate CuBr bonds [3.269 (1) Å] and nonclassical C-HBr hydrogen bonds connect the molecules, forming chains running parallel to the a axis. These chains are further linked via additional C-HBr hydrogen bonds into a three-dimensional network.
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