[Open access]

[Contents scheme]

Acta Cryst. (2013). E69, m72
[ doi:10.1107/S160053681205115X ]

Bis(diethylamido-[kappa]N)(diethylamine-[kappa]N)bis(2,6-diisopropylphenylamido-[kappa]N)zirconium(IV)

M. Zauliczny, R. Grubba, L. Ponikiewski and J. Pikies

Abstract: In the title compound, [Zr(C12H18N)2(C4H10N)2(C4H11N)] or [Zr(HNC6H3iPr2)2(NEt2)2(HNEt2)], which was obtained by the reaction of Zr(NEt)4 with iPr2C6H3NH2, the ZrIV atom is in a trigonal-bipiramidal geometry in which the N atoms from two iPr2C6H3NH and one NEt2 ligand occupy the equatorial positions, and the N atoms of an NEt2 and an Et2NH ligand occupy the apical positions. An intramolecular N-H...N contact occurs. There are two independent molecules in the asymmetric unit.


Copyright © International Union of Crystallography
IUCr Webmaster