Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 2 (February 2013)

organic compounds

Acta Cryst. (2013). E69, o167-o168    [ doi:10.1107/S1600536812051537 ]

(Pyridin-4-yl)methyl N'-(3-phenyl­allyl­idene)hydrazinecarbodithio­ate

M. L. Low, T. B. S. A. Ravoof, M. I. M. Tahir, K. A. Crouse and E. R. T. Tiekink

Abstract: In the title compound, C16H15N3S2, the central C2N2S2 residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the mol­ecule adopts an L-shape. The conformation about each of the N=C [1.290 (3) Å] and C=C [1.340 (3) Å] bonds is E. Supra­molecular chains along [1-10] are stabilized by N-H...N(pyridine) hydrogen bonding and these are connected into a double layer that stacks along the c-axis direction by C-H...[pi](pyridine) inter­actions.

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