Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 2 (February 2013)

organic compounds

qm2090 scheme

Acta Cryst. (2013). E69, o167-o168 [ doi:10.1107/S1600536812051537 ]

(Pyridin-4-yl)methyl N'-(3-phenylallylidene)hydrazinecarbodithioate

M. L. Low, T. B. S. A. Ravoof, M. I. M. Tahir, K. A. Crouse and E. R. T. Tiekink

Abstract: In the title compound, C₁₆H₁₅N₃S₂, the central C₂N₂S₂ residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the molecule adopts an L-shape. The conformation about each of the N=C [1.290 (3) Å] and C=C [1.340 (3) Å] bonds is E. Supramolecular chains along [1-10] are stabilized by N-HN(pyridine) hydrogen bonding and these are connected into a double layer that stacks along the c-axis direction by C-H [pi] (pyridine) interactions.


	Hyper-Text Markup Language (HTML) file [ doi:10.1107/S1600536812051537/qm2090sup0.html ] Supplementary materials

	Chemical Markup Language (CML) file (5.6 kbytes) [ doi:10.1107/S1600536812051537/qm2090Isup3.cml ] Supplementary material

Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

Search: From to Advanced search