Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 2 (February 2013)


organic compounds



rn2112 scheme

Acta Cryst. (2013). E69, o208-o209    [ doi:10.1107/S1600536812052038 ]

[2,7-Dihydroxy-8-(4-phenoxybenzoyl)naphthalen-1-yl](4-phenoxyphenyl)methanone

D. Hijikata, K. Sasagawa, S. Yoshiwaka, A. Okamoto and N. Yonezawa

Abstract: In the title compound, C36H24O6, the benzoyl groups at the 1- and 8-positions of the naphthalene system are in an anti orientation. Both carbonyl groups form intramolecular O-H...O hydrogen bonds with hydroxy groups affording six-membered rings. The benzene rings of the benzoyl groups make dihedral angles of 59.26 (13) and 59.09 (13)° with the naphthalene ring system. Zigzag C-H...O chains and ladder C-H...O chains between the phenoxybenzoyl groups along the ab diagonals form an undulating checkered sheet. The molecules are further connected into a three-dimensional network by C-H...[pi] interactions.


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[ doi:10.1107/S1600536812052038/rn2112sup0.html ]
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[ doi:10.1107/S1600536812052038/rn2112Isup3.cml ]
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