Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 2 (February 2013)


organic compounds



rz5035 scheme

Acta Cryst. (2013). E69, o210    [ doi:10.1107/S1600536812052026 ]

1-Benzoylnaphthalene-2,7-diyl dibenzoate

R. Sakamoto, K. Sasagawa, D. Hijikata, A. Okamoto and N. Yonezawa

Abstract: In the title compound, C31H20O5, the phenyl rings of the benzoyloxy and benzoyl groups are twisted away from the naphthalene ring system by 64.27 (6), 73.62 (5) and 80.41 (6)°. In the crystal, C-H...O hydrogen bonds and C-H...[pi] interactions link the molecules, forming tubular chains parallel to the b axis. The chains are further connected into a three-dimensional network by C-H...[pi] interactions and [pi]-[pi] stacking contacts [centroid-centroid distances = 3.622 (10)-3.866 (12) Å].


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