[Open access]

[Contents scheme]

Acta Cryst. (2013). E69, m103-m104
[ doi:10.1107/S1600536813000512 ]

Hexaaquacobalt(II) 2,2'-[naphthalene-1,8-diylbis(oxy)]diacetate dihydrate

H. F. Shi, T. Wu, P. G. Jiang, Z. Hao and M. M. Zhang

Abstract: In the title compound, [Co(H2O)6](C14H10O6)·2H2O, the 2,2'-[naphthalene-1,8-diylbis(oxy)]diacetate dianion L is not coordinated to the CoII ion. The asymmetric unit contains half of the L dianion, half of a [Co(H2O)6]2+ cation (both molecules being completed by inversion symmetry), and one water molecule. The crystal packing features O-H...O hydrogen bonding between the carboxylate groups, the aqua ligands and the hydrate water molecules.


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