Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 2 (February 2013)

organic compounds

Acta Cryst. (2013). E69, o303    [ doi:10.1107/S1600536813002110 ]

Acetonyltriphenyl­phospho­nium nitrate

T. Diop, L. Diop, M. Kuceráková and M. Dusek

Abstract: Crystals of the title salt, C21H20OP+·NO3-, are composed of acetonyltriphenyl­phospho­nium cations and nitrate anions that mainly inter­act through electrostatic forces. The P atom in the cation has a slightly distorted tetra­hedral environment, with C-P-C angles ranging from 104.79 (7) to 112.59 (6)°. The sum of O-N-O angles of the nitrate anion is 359.99°, reflecting its trigonal-planar character. C-H...O hydrogen bonds help to consolidate the crystal packing.

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