Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 2 (February 2013)


metal-organic compounds



zq2192 scheme

Acta Cryst. (2013). E69, m85    [ doi:10.1107/S1600536812050672 ]

Poly[bis([mu]2-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc]

Z. Song

Abstract: In the title compound, [Zn(C11H9N6)2]n, the ZnII atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmethyl)phenyl]tetrazolate ligands in a distorted tetrahedral geometry. The ligands bridge the ZnII atoms, leading to the formation of a two-dimensional network parallel to (010). The structure is further stabilized by C-H...N, C-H...[pi] and [pi]-[pi] [centroid-centroid distance = 3.7523 (11) Å] interactions within the network.


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