Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 3 (March 2013)

metal-organic compounds

bg2497 scheme

Acta Cryst. (2013). E69, m159 [ doi:10.1107/S1600536813004297 ]

(Pyridine-2-aldoximato-²N,N')bis[2-(pyridin-2-yl)phenyl-²C¹,N]iridium(III)

S. Pal and B. C. Singh

Abstract: In the title complex, [Ir(C₁₁H₈N)₂(C₆H₅N₂O)], the octahedrally coordinated Ir^III atom is bonded to two 2-(pyridin-2-yl)phenyl ligands, through two phenyl C and two pydidine N atoms, and to one pyridine-2-aldoxime ligand through a pyridine N and an oxime N atom. The oxime O atom of the aldoxime unit forms intermolecular C-HO hydrogen bonds, which result in a two-dimensional hydrogen-bonded polymeric network parallel to (100). C-H [pi] interactions are also observed.


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