Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 3 (March 2013)


metal-organic compounds



hb7032 scheme

Acta Cryst. (2013). E69, m156    [ doi:10.1107/S1600536813003747 ]

Bis{2-bromo-4-chloro-6-[(E)-(2,6-dimethylphenyl)iminomethyl]phenolato-[kappa]2N,O}cobalt(II)

G. Zhu and B.-J. Jiao

Abstract: In the title complex, [Co(C15H12BrClNO)2], the CoII ion is coordinated by two N,O-bidentate 2-bromo-4-chloro-6-[(E)-(2,6-dimethylphenyl)iminomethyl]phenolate ligands, generating a squashed CoN2O2 tetrahedral coordination geometry. The dihedral angles between the aromatic rings in the ligands are 82.60 (14) and 71.79 (14)°. The complex has approximate local noncrystallographic twofold symmetry. In the crystal, weak aromatic [pi]-[pi] stacking is observed [centroid-centroid separation = 3.6434 (18) Å].


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