Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 3 (March 2013)

organic compounds

Acta Cryst. (2013). E69, o382    [ doi:10.1107/S1600536813003966 ]

2,2-Dibenzyl­hydrazin-1-ium chloride

S. Tayamon, T. B. S. A. Ravoof, M. I. M. Tahir, K. A. Crouse and E. R. T. Tiekink

Abstract: In the title salt, C14H17N2+·Cl-, the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N-H...Cl hydrogen bonds, which lead to a supra­molecular undulating ribbon along the a axis comprising edge-shared eight-membered {...HNH...Cl}2 synthons. The chains are connected into layers in the ab plane by C-H...[pi] inter­actions.

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