supplementary materials


hg5286 scheme

Acta Cryst. (2013). E69, o402-o403    [ doi:10.1107/S1600536813002341 ]

2-(3,4-Dichlorophenyl)-N-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)acetamide

A. Mahan, R. J. Butcher, P. S. Nayak, B. Narayana and H. S. Yathirajan

Abstract top

In the title compound, C19H17Cl2N3O2, there are three molecules (A, B and C) in the asymmetric unit and each differs in the conformation adopted. As a result of steric repulsion, the amide group is rotated with respect to both the dichlorophenyl and 2,3-dihydro-1H-pyrazol-4-yl rings, making dihedral angles of 44.5 (2) and 56.2 (2)°, respectively in A, 51.1 (2) and 54.1 (2)° in B, and 53.8 (2) and 54.6 (2)° in C. The dihedral angles between the dichlorophenyl and 2,3-dihydro-1H-pyrazol-4-yl rings are 54.8 (2), 76.2 (2) and 77.5 (2)° in molecules A, B and C, respectively, while the 2,3-dihydro-1H-pyrazol-4-yl and phenyl rings make dihedral angles of 45.3 (2), 51.2 (2) and 42.8 (2)°, respectively. In the crystal, two of the molecules are linked through N-H...O hydrogen bonding to an adjoining molecule, forming dimers of the R22(10) type, while the third molecule forms such dimers with itself. C-H...O interactions link the dimers.

Comment top

N-Substituted 2-arylacetamides are very interesting compounds because of their structural similarity to the lateral chain of natural benzylpenicillin (Mijin et al., 2006, 2008). Amides are also used as ligands due to their excellent coordination abilities (Wu et al., 2008, 2010). Crystal structures of some acetamide derivatives viz., (2E)-1-(2,5-dimethoxyphenyl)-3-(3-nitrophenyl)prop-2-en-1-one, N-(4-bromophenyl)-2-(naphthalen-1-yl)acetamide, N-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-2-[4-(methylsulfanyl)phenyl]acetamide, N-(4-bromophenyl)-2-(4-chlorophenyl)acetamide (Fun et al., 2011a, 2011b, 2012a, 2012b) have been reported. Two related molecules with different dichloro substitution patterns have recently been published (Butcher et al., 2013a, 2013b). In view of the importance of amides we report herein the crystal structure of the title compound (I).

In the title compound, C19H17Cl2N3O2, there are three molecules in the asymmetric unit and each differs in the comformation adopted. In each molecule the amide group is planar but two of the molecules (B and C) are linked through N—H···O hydrogen bonding to an adjoining molecule forming dimers of the R22(10) type (Bernstein et al., 1995) while molecule A forms such dimers with itself. The major conformational difference between three molecules is seen in the dihedral angles between the dichlorophenyl and 2,3-dihydro-1H-pyrazol-4-yl rings which are 54.8 (2)°, 76.2 (2),° and 77.5 (2)° for A, B, and C, respectively. Due to steric repulsion the amide group is rotated with respect to both the dichlorophenyl and 2,3-dihydro-1H-pyrazol-4-yl rings with dihedral angles of 44.5 (2)° and 56.2 (2)° for A; 51.1 (2) and 54.1 (2) for B; and 53.8 (2) and 54.6 (2) for C. All other metrical parameters are in the normal ranges (Allen, 2002).

Related literature top

For graph-set description of hydrogen-bonding patterns, see: Bernstein et al. (1995). For related structures, see: Fun et al. (2011a,b, 2012a,b). For similar structures but with differing dichloro substitution, see: Butcher et al. (2013a,b). For a description of the Cambridge Structural Database, see: Allen (2002). For the biological activity of N-substituted 2-arylacetamides, see: Mijin & Marinkovic (2006); Mijin et al. (2008). For the coordination abilities of amides, see: Wu et al. (2008, 2010).

Experimental top

3,4-Dichlorophenylacetic acid (0.240 g, 1 mmol) and 4-aminoantipyrine (0.203 g, 1 mmol), 1-ethyl-3-(3-dimethylaminopropyl)-carbodiimide hydrochloride (1.0 g, 0.01 mol) and were dissolved in dichloromethane (20 ml). The mixture was stirred in presence of triethylamine at 273 K for about 3 h. The contents were poured into 100 ml of ice-cold aqueous hydrochloric acid with stirring, which was extracted thrice with dichloromethane. The organic layer was washed with saturated NaHCO3 solution and brine solution, dried and concentrated under reduced pressure to give the title compound (I). Single crystals were grown from methylene chloride by the slow evaporation method (m.p.: 473–475 K).

Refinement top

The H atoms were placed in calculated positions and refined in the riding mode: N—H = 0.88 Å, C—H = 0.95–0.99 Å with Uiso(H) = 1.5Ueq(C) for methyl H atoms and = 1.2Ueq(O,C) for other H atoms.

Computing details top

Data collection: CrysAlis PRO (Agilent, 2011); cell refinement: CrysAlis PRO (Agilent, 2011); data reduction: CrysAlis PRO (Agilent, 2011); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The molecular structure of the title molecule with the atom numbering. The displacement ellipsoids are drawn at the 30% probability level.
[Figure 2] Fig. 2. The crystal packing of the title compound, viewed along the b axis. Hydrogen bonds are shown as dashed lines - see Table 1 for details.
2-(3,4-Dichlorophenyl)-N-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro- 1H-pyrazol-4-yl)acetamide top
Crystal data top
C19H17Cl2N3O2F(000) = 2424
Mr = 390.26Dx = 1.419 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybcCell parameters from 4632 reflections
a = 17.2064 (8) Åθ = 3.1–37.6°
b = 20.7984 (9) ŵ = 0.37 mm1
c = 15.6102 (7) ÅT = 123 K
β = 101.213 (4)°Prism, colorless
V = 5479.7 (4) Å30.51 × 0.34 × 0.10 mm
Z = 12
Data collection top
Agilent Xcalibur (Ruby, Gemini)
diffractometer
27521 independent reflections
Radiation source: Enhance (Mo) X-ray Source11938 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.076
Detector resolution: 10.5081 pixels mm-1θmax = 37.7°, θmin = 3.1°
ω scansh = 2825
Absorption correction: analytical
[CrysAlis PRO (Agilent, 2011) based on expressions derived by Clark & Reid (1995)]
k = 3525
Tmin = 0.743, Tmax = 0.932l = 2623
54403 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.119Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.345H-atom parameters constrained
S = 1.02 w = 1/[σ2(Fo2) + (0.1574P)2]
where P = (Fo2 + 2Fc2)/3
27521 reflections(Δ/σ)max = 0.001
709 parametersΔρmax = 3.46 e Å3
0 restraintsΔρmin = 0.84 e Å3
Crystal data top
C19H17Cl2N3O2V = 5479.7 (4) Å3
Mr = 390.26Z = 12
Monoclinic, P21/cMo Kα radiation
a = 17.2064 (8) ŵ = 0.37 mm1
b = 20.7984 (9) ÅT = 123 K
c = 15.6102 (7) Å0.51 × 0.34 × 0.10 mm
β = 101.213 (4)°
Data collection top
Agilent Xcalibur (Ruby, Gemini)
diffractometer
27521 independent reflections
Absorption correction: analytical
[CrysAlis PRO (Agilent, 2011) based on expressions derived by Clark & Reid (1995)]
11938 reflections with I > 2σ(I)
Tmin = 0.743, Tmax = 0.932Rint = 0.076
54403 measured reflectionsθmax = 37.7°
Refinement top
R[F2 > 2σ(F2)] = 0.119H-atom parameters constrained
wR(F2) = 0.345Δρmax = 3.46 e Å3
S = 1.02Δρmin = 0.84 e Å3
27521 reflectionsAbsolute structure: ?
709 parametersFlack parameter: ?
0 restraintsRogers parameter: ?
Special details top

Experimental. Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid. (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Cl1A0.96725 (6)0.40403 (6)0.84456 (8)0.0462 (3)
Cl2A1.02211 (6)0.54928 (7)0.85730 (7)0.0502 (3)
O1A0.68657 (13)0.39601 (11)0.88454 (14)0.0210 (4)
O2A0.44835 (12)0.49727 (10)0.89719 (13)0.0174 (4)
N1A0.60317 (14)0.43172 (11)0.97043 (16)0.0157 (4)
H1AA0.59960.45291.01830.019*
N2A0.44192 (14)0.33263 (11)0.85826 (16)0.0166 (4)
N3A0.40983 (14)0.39502 (11)0.84534 (16)0.0160 (4)
C1A0.80792 (19)0.48640 (17)0.9654 (2)0.0260 (7)
C2A0.85147 (18)0.44182 (16)0.9279 (2)0.0231 (6)
H2AA0.83650.39780.92580.028*
C3A0.9165 (2)0.4607 (2)0.8933 (2)0.0343 (8)
C4A0.9403 (2)0.5249 (2)0.8975 (2)0.0342 (8)
C5A0.8975 (2)0.5697 (2)0.9352 (3)0.0380 (9)
H5AA0.91370.61340.93910.046*
C6A0.8306 (2)0.55102 (19)0.9675 (2)0.0334 (8)
H6AA0.80050.58240.99100.040*
C7A0.73992 (18)0.46564 (17)1.0061 (2)0.0234 (6)
H7AA0.71600.50441.02710.028*
H7AB0.76100.43881.05780.028*
C8A0.67481 (16)0.42806 (14)0.94674 (17)0.0152 (5)
C9A0.53436 (15)0.40317 (13)0.92196 (17)0.0143 (5)
C10A0.51996 (16)0.34018 (13)0.90096 (17)0.0142 (5)
C11A0.57441 (18)0.28372 (14)0.9175 (2)0.0201 (5)
H11A0.61410.29110.97080.030*
H11B0.60110.27800.86800.030*
H11C0.54380.24500.92460.030*
C12A0.4225 (2)0.29090 (15)0.7810 (2)0.0230 (6)
H12A0.44750.24880.79430.034*
H12B0.44220.31050.73220.034*
H12C0.36490.28560.76490.034*
C13A0.46347 (16)0.43918 (13)0.88913 (17)0.0136 (5)
C14A0.32692 (17)0.40479 (15)0.82140 (18)0.0172 (5)
C15A0.27399 (19)0.36295 (17)0.8493 (2)0.0234 (6)
H15A0.29260.32660.88410.028*
C16A0.1929 (2)0.3754 (2)0.8251 (2)0.0332 (8)
H16A0.15610.34670.84310.040*
C17A0.1657 (2)0.4279 (2)0.7762 (3)0.0367 (9)
H17A0.11040.43610.76150.044*
C18A0.2186 (2)0.4698 (2)0.7476 (2)0.0334 (8)
H18A0.19930.50590.71270.040*
C19A0.29997 (18)0.45836 (16)0.7703 (2)0.0223 (6)
H19A0.33650.48670.75130.027*
Cl1B0.03779 (6)0.59135 (6)0.65631 (7)0.0425 (3)
Cl2B0.07149 (5)0.56646 (5)0.47093 (8)0.0413 (3)
O1B0.31484 (12)0.56614 (11)0.61156 (14)0.0214 (4)
O2B0.55541 (12)0.66284 (9)0.59479 (13)0.0168 (4)
N1B0.40028 (14)0.59847 (11)0.52644 (15)0.0149 (4)
H1BA0.40400.61740.47700.018*
N2B0.56017 (14)0.50006 (11)0.64305 (15)0.0158 (4)
N3B0.59287 (14)0.56181 (11)0.65139 (16)0.0154 (4)
C1B0.18424 (19)0.62618 (16)0.4936 (2)0.0252 (6)
C2B0.15246 (18)0.61974 (16)0.5682 (2)0.0235 (6)
H2BA0.18460.62770.62390.028*
C3B0.0743 (2)0.60175 (17)0.5619 (2)0.0291 (7)
C4B0.02603 (19)0.59001 (16)0.4803 (2)0.0282 (7)
C5B0.0574 (2)0.59658 (19)0.4055 (3)0.0339 (8)
H5BA0.02490.58930.34980.041*
C6B0.1362 (2)0.61376 (18)0.4118 (2)0.0296 (7)
H6BA0.15780.61710.36040.035*
C7B0.26904 (18)0.64545 (17)0.4993 (2)0.0266 (7)
H7BA0.27720.68850.52680.032*
H7BB0.27970.64910.43940.032*
C8B0.32919 (16)0.59851 (14)0.55152 (18)0.0159 (5)
C9B0.46845 (16)0.56950 (13)0.57595 (17)0.0136 (5)
C10B0.48187 (16)0.50685 (13)0.60107 (18)0.0147 (5)
C11B0.42690 (18)0.45144 (14)0.5903 (2)0.0196 (5)
H11D0.38530.45800.53850.029*
H11E0.40280.44760.64200.029*
H11F0.45620.41200.58320.029*
C12B0.5825 (2)0.45914 (14)0.72096 (19)0.0218 (6)
H12D0.55880.41650.70900.033*
H12E0.56330.47870.77010.033*
H12F0.64030.45510.73570.033*
C13B0.53967 (16)0.60554 (13)0.60611 (17)0.0133 (5)
C14B0.67664 (17)0.57215 (14)0.67190 (18)0.0167 (5)
C15B0.72831 (19)0.53193 (17)0.6391 (2)0.0251 (6)
H15B0.70900.49550.60480.030*
C16B0.8090 (2)0.5461 (2)0.6575 (3)0.0346 (8)
H16B0.84520.51910.63560.042*
C17B0.8366 (2)0.5992 (2)0.7076 (3)0.0343 (8)
H17B0.89160.60920.71870.041*
C18B0.7847 (2)0.63768 (19)0.7415 (2)0.0300 (7)
H18B0.80430.67340.77700.036*
C19B0.70414 (17)0.62481 (16)0.72430 (19)0.0209 (6)
H19B0.66840.65130.74770.025*
Cl1C0.95668 (6)0.74477 (6)0.30440 (7)0.0418 (3)
Cl2C1.07466 (6)0.77783 (5)0.48017 (8)0.0445 (3)
O1C0.68889 (12)0.77189 (11)0.37835 (14)0.0199 (4)
O2C0.44782 (12)0.67409 (10)0.39335 (13)0.0177 (4)
N1C0.60697 (14)0.73495 (12)0.46543 (16)0.0165 (4)
H1CA0.60410.71360.51340.020*
N2C0.44993 (14)0.83872 (11)0.35446 (15)0.0148 (4)
N3C0.41482 (14)0.77732 (12)0.34240 (16)0.0153 (4)
C1C0.82344 (19)0.71341 (16)0.4839 (2)0.0249 (6)
C2C0.85001 (18)0.71832 (16)0.4053 (2)0.0249 (6)
H2CA0.81510.70790.35210.030*
C3C0.92665 (19)0.73824 (17)0.4035 (2)0.0279 (7)
C4C0.9792 (2)0.75366 (17)0.4810 (3)0.0304 (7)
C5C0.9537 (2)0.74789 (18)0.5595 (3)0.0317 (8)
H5CA0.98900.75710.61290.038*
C6C0.8762 (2)0.72867 (18)0.5603 (2)0.0288 (7)
H6CA0.85910.72590.61450.035*
C7C0.74038 (17)0.69158 (16)0.4860 (2)0.0232 (6)
H7CA0.73430.68770.54750.028*
H7CB0.73190.64850.45890.028*
C8C0.67712 (16)0.73747 (13)0.43810 (18)0.0158 (5)
C9C0.53850 (16)0.76571 (13)0.41904 (17)0.0134 (5)
C10C0.52724 (16)0.82917 (13)0.39794 (17)0.0143 (5)
C11C0.58400 (17)0.88362 (14)0.4159 (2)0.0187 (5)
H11G0.62310.87470.46920.028*
H11H0.55520.92320.42360.028*
H11I0.61120.88880.36670.028*
C12C0.4357 (2)0.87879 (15)0.27529 (19)0.0226 (6)
H12G0.46070.92090.28860.034*
H12H0.37850.88440.25490.034*
H12I0.45840.85780.22960.034*
C13C0.46585 (16)0.73144 (14)0.38594 (17)0.0146 (5)
C14C0.33155 (17)0.77181 (15)0.31674 (19)0.0183 (5)
C15C0.28252 (19)0.81775 (18)0.3418 (2)0.0266 (7)
H15C0.30440.85320.37680.032*
C16C0.2006 (2)0.8117 (2)0.3154 (3)0.0416 (10)
H16C0.16650.84340.33180.050*
C17C0.1691 (2)0.7599 (2)0.2656 (3)0.0464 (11)
H17C0.11330.75590.24760.056*
C18C0.2190 (2)0.7133 (2)0.2414 (2)0.0358 (9)
H18C0.19680.67750.20760.043*
C19C0.30039 (18)0.71880 (16)0.2661 (2)0.0222 (6)
H19C0.33440.68730.24920.027*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Cl1A0.0284 (5)0.0573 (7)0.0586 (7)0.0007 (4)0.0225 (5)0.0106 (5)
Cl2A0.0303 (5)0.0761 (8)0.0440 (6)0.0183 (5)0.0069 (4)0.0174 (5)
O1A0.0171 (9)0.0288 (12)0.0183 (9)0.0018 (8)0.0063 (8)0.0073 (9)
O2A0.0188 (9)0.0130 (9)0.0207 (9)0.0011 (7)0.0048 (8)0.0006 (8)
N1A0.0146 (10)0.0155 (11)0.0174 (10)0.0014 (8)0.0038 (8)0.0040 (9)
N2A0.0176 (10)0.0135 (11)0.0192 (11)0.0011 (8)0.0052 (9)0.0002 (9)
N3A0.0152 (10)0.0132 (11)0.0194 (11)0.0019 (8)0.0027 (9)0.0005 (9)
C1A0.0208 (14)0.0319 (18)0.0239 (15)0.0060 (12)0.0010 (12)0.0019 (13)
C2A0.0154 (12)0.0251 (15)0.0290 (15)0.0030 (11)0.0047 (11)0.0008 (13)
C3A0.0208 (15)0.052 (2)0.0297 (17)0.0008 (15)0.0039 (13)0.0015 (17)
C4A0.0221 (15)0.051 (2)0.0276 (16)0.0131 (15)0.0010 (13)0.0110 (16)
C5A0.038 (2)0.032 (2)0.043 (2)0.0128 (16)0.0051 (17)0.0101 (17)
C6A0.0343 (19)0.0319 (19)0.0338 (18)0.0052 (15)0.0065 (15)0.0017 (15)
C7A0.0182 (13)0.0321 (17)0.0197 (13)0.0086 (12)0.0035 (11)0.0027 (12)
C8A0.0137 (11)0.0178 (13)0.0143 (11)0.0019 (9)0.0035 (9)0.0007 (10)
C9A0.0125 (10)0.0147 (12)0.0158 (11)0.0010 (9)0.0030 (9)0.0013 (10)
C10A0.0163 (11)0.0145 (12)0.0124 (11)0.0007 (9)0.0046 (9)0.0008 (9)
C11A0.0212 (13)0.0168 (13)0.0239 (14)0.0001 (10)0.0082 (11)0.0010 (11)
C12A0.0327 (16)0.0170 (14)0.0183 (13)0.0042 (12)0.0028 (12)0.0053 (11)
C13A0.0144 (11)0.0131 (12)0.0137 (11)0.0005 (9)0.0038 (9)0.0001 (9)
C14A0.0155 (11)0.0218 (14)0.0140 (11)0.0041 (10)0.0019 (9)0.0018 (10)
C15A0.0210 (14)0.0300 (16)0.0190 (13)0.0073 (12)0.0031 (11)0.0016 (12)
C16A0.0180 (14)0.051 (2)0.0321 (17)0.0102 (14)0.0073 (13)0.0029 (17)
C17A0.0133 (13)0.059 (3)0.0374 (19)0.0007 (15)0.0029 (13)0.0074 (18)
C18A0.0220 (15)0.041 (2)0.0350 (18)0.0077 (14)0.0009 (14)0.0092 (16)
C19A0.0180 (13)0.0274 (16)0.0212 (13)0.0014 (11)0.0035 (11)0.0024 (12)
Cl1B0.0258 (4)0.0647 (7)0.0410 (5)0.0036 (4)0.0167 (4)0.0069 (5)
Cl2B0.0203 (4)0.0342 (5)0.0670 (7)0.0011 (3)0.0027 (4)0.0015 (5)
O1B0.0162 (9)0.0290 (12)0.0198 (10)0.0004 (8)0.0057 (8)0.0062 (9)
O2B0.0181 (9)0.0124 (9)0.0208 (9)0.0001 (7)0.0056 (8)0.0011 (8)
N1B0.0141 (10)0.0167 (11)0.0146 (10)0.0005 (8)0.0046 (8)0.0048 (9)
N2B0.0175 (10)0.0117 (10)0.0178 (10)0.0001 (8)0.0025 (9)0.0008 (9)
N3B0.0126 (9)0.0137 (10)0.0189 (10)0.0009 (8)0.0007 (8)0.0004 (9)
C1B0.0196 (14)0.0250 (16)0.0308 (16)0.0074 (12)0.0042 (12)0.0083 (13)
C2B0.0170 (13)0.0286 (16)0.0253 (14)0.0057 (11)0.0048 (11)0.0009 (13)
C3B0.0211 (15)0.0292 (17)0.0376 (18)0.0044 (13)0.0069 (13)0.0045 (15)
C4B0.0174 (13)0.0233 (16)0.0427 (19)0.0032 (11)0.0028 (13)0.0007 (15)
C5B0.0255 (16)0.036 (2)0.0376 (19)0.0051 (14)0.0010 (15)0.0018 (16)
C6B0.0270 (16)0.0317 (18)0.0294 (16)0.0054 (13)0.0040 (14)0.0027 (14)
C7B0.0188 (14)0.0279 (16)0.0343 (17)0.0064 (12)0.0080 (12)0.0146 (14)
C8B0.0137 (11)0.0172 (13)0.0167 (12)0.0007 (9)0.0027 (9)0.0027 (10)
C9B0.0136 (11)0.0141 (12)0.0137 (11)0.0002 (9)0.0040 (9)0.0021 (9)
C10B0.0149 (11)0.0140 (12)0.0163 (11)0.0003 (9)0.0058 (9)0.0003 (10)
C11B0.0208 (13)0.0140 (12)0.0249 (14)0.0014 (10)0.0070 (11)0.0018 (11)
C12B0.0311 (16)0.0143 (13)0.0182 (13)0.0005 (11)0.0000 (12)0.0052 (11)
C13B0.0155 (11)0.0128 (12)0.0127 (11)0.0013 (9)0.0050 (9)0.0001 (9)
C14B0.0149 (11)0.0199 (13)0.0146 (11)0.0020 (10)0.0011 (9)0.0009 (10)
C15B0.0192 (13)0.0280 (16)0.0283 (15)0.0072 (12)0.0049 (12)0.0054 (13)
C16B0.0200 (15)0.042 (2)0.043 (2)0.0097 (14)0.0095 (14)0.0020 (17)
C17B0.0152 (14)0.044 (2)0.043 (2)0.0000 (14)0.0029 (14)0.0046 (17)
C18B0.0219 (15)0.0368 (19)0.0291 (16)0.0074 (13)0.0005 (13)0.0029 (15)
C19B0.0164 (12)0.0272 (15)0.0186 (13)0.0007 (11)0.0024 (10)0.0022 (12)
Cl1C0.0249 (4)0.0613 (7)0.0422 (5)0.0078 (4)0.0135 (4)0.0122 (5)
Cl2C0.0220 (4)0.0449 (6)0.0663 (7)0.0046 (4)0.0080 (4)0.0016 (5)
O1C0.0166 (9)0.0238 (11)0.0206 (10)0.0024 (8)0.0065 (8)0.0072 (8)
O2C0.0207 (10)0.0123 (9)0.0207 (10)0.0022 (7)0.0054 (8)0.0009 (8)
N1C0.0165 (10)0.0167 (11)0.0169 (10)0.0024 (8)0.0047 (9)0.0058 (9)
N2C0.0147 (10)0.0141 (11)0.0153 (10)0.0016 (8)0.0018 (8)0.0008 (8)
N3C0.0127 (9)0.0161 (11)0.0172 (10)0.0001 (8)0.0029 (8)0.0017 (9)
C1C0.0189 (13)0.0254 (16)0.0295 (16)0.0065 (11)0.0020 (12)0.0055 (13)
C2C0.0153 (13)0.0280 (16)0.0312 (16)0.0034 (11)0.0037 (12)0.0039 (14)
C3C0.0160 (13)0.0318 (18)0.0360 (18)0.0071 (12)0.0053 (12)0.0059 (15)
C4C0.0190 (14)0.0248 (16)0.048 (2)0.0027 (12)0.0067 (14)0.0030 (15)
C5C0.0240 (16)0.0319 (18)0.0371 (19)0.0006 (13)0.0005 (14)0.0017 (15)
C6C0.0254 (16)0.0325 (18)0.0270 (16)0.0048 (13)0.0011 (13)0.0000 (14)
C7C0.0150 (12)0.0229 (15)0.0324 (16)0.0053 (10)0.0066 (11)0.0108 (13)
C8C0.0141 (11)0.0158 (12)0.0176 (12)0.0012 (9)0.0034 (9)0.0005 (10)
C9C0.0170 (11)0.0125 (11)0.0123 (10)0.0017 (9)0.0065 (9)0.0011 (9)
C10C0.0139 (11)0.0148 (12)0.0150 (11)0.0003 (9)0.0048 (9)0.0012 (10)
C11C0.0201 (13)0.0132 (12)0.0236 (13)0.0015 (10)0.0061 (11)0.0012 (11)
C12C0.0326 (16)0.0183 (14)0.0153 (12)0.0018 (12)0.0006 (12)0.0043 (11)
C13C0.0142 (11)0.0166 (12)0.0139 (11)0.0021 (9)0.0052 (9)0.0009 (10)
C14C0.0160 (12)0.0228 (14)0.0162 (12)0.0009 (10)0.0033 (10)0.0022 (11)
C15C0.0188 (13)0.0335 (18)0.0267 (15)0.0070 (12)0.0025 (12)0.0023 (14)
C16C0.0230 (17)0.060 (3)0.043 (2)0.0134 (17)0.0081 (16)0.008 (2)
C17C0.0173 (16)0.073 (3)0.046 (2)0.0040 (18)0.0006 (16)0.000 (2)
C18C0.0232 (16)0.052 (2)0.0305 (17)0.0131 (16)0.0020 (14)0.0031 (17)
C19C0.0201 (13)0.0289 (16)0.0179 (13)0.0048 (12)0.0042 (11)0.0021 (12)
Geometric parameters (Å, º) top
Cl1A—C3A1.729 (4)C7B—H7BA0.9900
Cl2A—C4A1.726 (4)C7B—H7BB0.9900
O1A—C8A1.227 (3)C9B—C10B1.367 (4)
O2A—C13A1.247 (3)C9B—C13B1.435 (4)
N1A—C8A1.356 (3)C10B—C11B1.480 (4)
N1A—C9A1.406 (4)C11B—H11D0.9800
N1A—H1AA0.8800C11B—H11E0.9800
N2A—C10A1.387 (4)C11B—H11F0.9800
N2A—N3A1.409 (3)C12B—H12D0.9800
N2A—C12A1.471 (4)C12B—H12E0.9800
N3A—C13A1.385 (4)C12B—H12F0.9800
N3A—C14A1.417 (4)C14B—C15B1.389 (4)
C1A—C2A1.392 (5)C14B—C19B1.394 (4)
C1A—C6A1.398 (5)C15B—C16B1.394 (5)
C1A—C7A1.499 (4)C15B—H15B0.9500
C2A—C3A1.389 (5)C16B—C17B1.383 (6)
C2A—H2AA0.9500C16B—H16B0.9500
C3A—C4A1.395 (6)C17B—C18B1.380 (5)
C4A—C5A1.387 (6)C17B—H17B0.9500
C5A—C6A1.398 (5)C18B—C19B1.385 (4)
C5A—H5AA0.9500C18B—H18B0.9500
C6A—H6AA0.9500C19B—H19B0.9500
C7A—C8A1.523 (4)Cl1C—C3C1.728 (4)
C7A—H7AA0.9900Cl2C—C4C1.720 (4)
C7A—H7AB0.9900O1C—C8C1.224 (3)
C9A—C10A1.361 (4)O2C—C13C1.244 (3)
C9A—C13A1.438 (4)N1C—C8C1.357 (4)
C10A—C11A1.493 (4)N1C—C9C1.411 (4)
C11A—H11A0.9800N1C—H1CA0.8800
C11A—H11B0.9800N2C—C10C1.385 (4)
C11A—H11C0.9800N2C—N3C1.410 (3)
C12A—H12A0.9800N2C—C12C1.471 (4)
C12A—H12B0.9800N3C—C13C1.383 (4)
C12A—H12C0.9800N3C—C14C1.415 (4)
C14A—C15A1.389 (4)C1C—C6C1.388 (5)
C14A—C19A1.396 (4)C1C—C2C1.394 (5)
C15A—C16A1.397 (5)C1C—C7C1.506 (4)
C15A—H15A0.9500C2C—C3C1.388 (5)
C16A—C17A1.363 (6)C2C—H2CA0.9500
C16A—H16A0.9500C3C—C4C1.399 (5)
C17A—C18A1.393 (5)C4C—C5C1.386 (6)
C17A—H17A0.9500C5C—C6C1.394 (5)
C18A—C19A1.396 (5)C5C—H5CA0.9500
C18A—H18A0.9500C6C—H6CA0.9500
C19A—H19A0.9500C7C—C8C1.529 (4)
Cl1B—C3B1.725 (4)C7C—H7CA0.9900
Cl2B—C4B1.727 (3)C7C—H7CB0.9900
O1B—C8B1.218 (3)C9C—C10C1.365 (4)
O2B—C13B1.242 (3)C9C—C13C1.444 (4)
N1B—C8B1.355 (3)C10C—C11C1.486 (4)
N1B—C9B1.408 (3)C11C—H11G0.9800
N1B—H1BA0.8800C11C—H11H0.9800
N2B—C10B1.386 (4)C11C—H11I0.9800
N2B—N3B1.398 (3)C12C—H12G0.9800
N2B—C12B1.473 (4)C12C—H12H0.9800
N3B—C13B1.383 (3)C12C—H12I0.9800
N3B—C14B1.431 (4)C14C—C15C1.381 (4)
C1B—C2B1.386 (5)C14C—C19C1.401 (4)
C1B—C6B1.403 (5)C15C—C16C1.396 (5)
C1B—C7B1.499 (5)C15C—H15C0.9500
C2B—C3B1.381 (5)C16C—C17C1.376 (6)
C2B—H2BA0.9500C16C—H16C0.9500
C3B—C4B1.401 (5)C17C—C18C1.394 (6)
C4B—C5B1.384 (5)C17C—H17C0.9500
C5B—C6B1.388 (5)C18C—C19C1.384 (5)
C5B—H5BA0.9500C18C—H18C0.9500
C6B—H6BA0.9500C19C—H19C0.9500
C7B—C8B1.536 (4)
C8A—N1A—C9A123.0 (2)N1B—C9B—C13B121.6 (2)
C8A—N1A—H1AA118.5C9B—C10B—N2B109.1 (2)
C9A—N1A—H1AA118.5C9B—C10B—C11B129.9 (3)
C10A—N2A—N3A106.3 (2)N2B—C10B—C11B121.0 (2)
C10A—N2A—C12A120.3 (2)C10B—C11B—H11D109.5
N3A—N2A—C12A113.9 (2)C10B—C11B—H11E109.5
C13A—N3A—N2A109.6 (2)H11D—C11B—H11E109.5
C13A—N3A—C14A125.1 (2)C10B—C11B—H11F109.5
N2A—N3A—C14A121.1 (2)H11D—C11B—H11F109.5
C2A—C1A—C6A118.6 (3)H11E—C11B—H11F109.5
C2A—C1A—C7A121.0 (3)N2B—C12B—H12D109.5
C6A—C1A—C7A120.3 (3)N2B—C12B—H12E109.5
C3A—C2A—C1A121.0 (3)H12D—C12B—H12E109.5
C3A—C2A—H2AA119.5N2B—C12B—H12F109.5
C1A—C2A—H2AA119.5H12D—C12B—H12F109.5
C2A—C3A—C4A120.2 (4)H12E—C12B—H12F109.5
C2A—C3A—Cl1A119.5 (3)O2B—C13B—N3B124.2 (3)
C4A—C3A—Cl1A120.3 (3)O2B—C13B—C9B130.5 (3)
C5A—C4A—C3A119.2 (3)N3B—C13B—C9B105.2 (2)
C5A—C4A—Cl2A119.7 (3)C15B—C14B—C19B121.4 (3)
C3A—C4A—Cl2A121.1 (3)C15B—C14B—N3B121.1 (3)
C4A—C5A—C6A120.6 (4)C19B—C14B—N3B117.5 (3)
C4A—C5A—H5AA119.7C14B—C15B—C16B118.7 (3)
C6A—C5A—H5AA119.7C14B—C15B—H15B120.6
C5A—C6A—C1A120.3 (4)C16B—C15B—H15B120.6
C5A—C6A—H6AA119.8C17B—C16B—C15B120.3 (3)
C1A—C6A—H6AA119.8C17B—C16B—H16B119.9
C1A—C7A—C8A115.6 (3)C15B—C16B—H16B119.9
C1A—C7A—H7AA108.4C18B—C17B—C16B120.2 (3)
C8A—C7A—H7AA108.4C18B—C17B—H17B119.9
C1A—C7A—H7AB108.4C16B—C17B—H17B119.9
C8A—C7A—H7AB108.4C17B—C18B—C19B120.8 (3)
H7AA—C7A—H7AB107.4C17B—C18B—H18B119.6
O1A—C8A—N1A123.0 (3)C19B—C18B—H18B119.6
O1A—C8A—C7A123.1 (3)C18B—C19B—C14B118.6 (3)
N1A—C8A—C7A113.9 (2)C18B—C19B—H19B120.7
C10A—C9A—N1A129.1 (3)C14B—C19B—H19B120.7
C10A—C9A—C13A108.3 (2)C8C—N1C—C9C121.7 (2)
N1A—C9A—C13A122.6 (2)C8C—N1C—H1CA119.1
C9A—C10A—N2A109.8 (2)C9C—N1C—H1CA119.1
C9A—C10A—C11A129.5 (3)C10C—N2C—N3C106.3 (2)
N2A—C10A—C11A120.7 (2)C10C—N2C—C12C118.7 (2)
C10A—C11A—H11A109.5N3C—N2C—C12C113.8 (2)
C10A—C11A—H11B109.5C13C—N3C—N2C110.2 (2)
H11A—C11A—H11B109.5C13C—N3C—C14C126.5 (2)
C10A—C11A—H11C109.5N2C—N3C—C14C119.7 (2)
H11A—C11A—H11C109.5C6C—C1C—C2C117.9 (3)
H11B—C11A—H11C109.5C6C—C1C—C7C121.0 (3)
N2A—C12A—H12A109.5C2C—C1C—C7C121.1 (3)
N2A—C12A—H12B109.5C3C—C2C—C1C121.0 (3)
H12A—C12A—H12B109.5C3C—C2C—H2CA119.5
N2A—C12A—H12C109.5C1C—C2C—H2CA119.5
H12A—C12A—H12C109.5C2C—C3C—C4C120.5 (3)
H12B—C12A—H12C109.5C2C—C3C—Cl1C119.5 (3)
O2A—C13A—N3A124.1 (3)C4C—C3C—Cl1C120.0 (3)
O2A—C13A—C9A130.4 (3)C5C—C4C—C3C118.8 (3)
N3A—C13A—C9A105.6 (2)C5C—C4C—Cl2C119.9 (3)
C15A—C14A—C19A120.9 (3)C3C—C4C—Cl2C121.2 (3)
C15A—C14A—N3A121.0 (3)C4C—C5C—C6C120.1 (3)
C19A—C14A—N3A118.1 (3)C4C—C5C—H5CA120.0
C14A—C15A—C16A118.7 (3)C6C—C5C—H5CA120.0
C14A—C15A—H15A120.6C1C—C6C—C5C121.6 (3)
C16A—C15A—H15A120.6C1C—C6C—H6CA119.2
C17A—C16A—C15A121.0 (3)C5C—C6C—H6CA119.2
C17A—C16A—H16A119.5C1C—C7C—C8C112.9 (3)
C15A—C16A—H16A119.5C1C—C7C—H7CA109.0
C16A—C17A—C18A120.4 (3)C8C—C7C—H7CA109.0
C16A—C17A—H17A119.8C1C—C7C—H7CB109.0
C18A—C17A—H17A119.8C8C—C7C—H7CB109.0
C17A—C18A—C19A119.8 (3)H7CA—C7C—H7CB107.8
C17A—C18A—H18A120.1O1C—C8C—N1C123.5 (3)
C19A—C18A—H18A120.1O1C—C8C—C7C122.0 (3)
C14A—C19A—C18A119.1 (3)N1C—C8C—C7C114.5 (2)
C14A—C19A—H19A120.5C10C—C9C—N1C128.9 (3)
C18A—C19A—H19A120.5C10C—C9C—C13C108.6 (2)
C8B—N1B—C9B123.0 (2)N1C—C9C—C13C122.6 (2)
C8B—N1B—H1BA118.5C9C—C10C—N2C109.6 (2)
C9B—N1B—H1BA118.5C9C—C10C—C11C129.4 (3)
C10B—N2B—N3B106.7 (2)N2C—C10C—C11C121.1 (2)
C10B—N2B—C12B121.6 (2)C10C—C11C—H11G109.5
N3B—N2B—C12B114.7 (2)C10C—C11C—H11H109.5
C13B—N3B—N2B110.0 (2)H11G—C11C—H11H109.5
C13B—N3B—C14B123.6 (2)C10C—C11C—H11I109.5
N2B—N3B—C14B121.9 (2)H11G—C11C—H11I109.5
C2B—C1B—C6B119.2 (3)H11H—C11C—H11I109.5
C2B—C1B—C7B121.0 (3)N2C—C12C—H12G109.5
C6B—C1B—C7B119.8 (3)N2C—C12C—H12H109.5
C3B—C2B—C1B120.2 (3)H12G—C12C—H12H109.5
C3B—C2B—H2BA119.9N2C—C12C—H12I109.5
C1B—C2B—H2BA119.9H12G—C12C—H12I109.5
C2B—C3B—C4B120.6 (3)H12H—C12C—H12I109.5
C2B—C3B—Cl1B119.0 (3)O2C—C13C—N3C124.2 (3)
C4B—C3B—Cl1B120.4 (3)O2C—C13C—C9C130.9 (3)
C5B—C4B—C3B119.3 (3)N3C—C13C—C9C105.0 (2)
C5B—C4B—Cl2B119.3 (3)C15C—C14C—C19C121.1 (3)
C3B—C4B—Cl2B121.4 (3)C15C—C14C—N3C120.3 (3)
C4B—C5B—C6B120.1 (3)C19C—C14C—N3C118.6 (3)
C4B—C5B—H5BA119.9C14C—C15C—C16C119.5 (3)
C6B—C5B—H5BA119.9C14C—C15C—H15C120.3
C5B—C6B—C1B120.4 (3)C16C—C15C—H15C120.3
C5B—C6B—H6BA119.8C17C—C16C—C15C120.1 (4)
C1B—C6B—H6BA119.8C17C—C16C—H16C120.0
C1B—C7B—C8B114.1 (3)C15C—C16C—H16C120.0
C1B—C7B—H7BA108.7C16C—C17C—C18C120.2 (4)
C8B—C7B—H7BA108.7C16C—C17C—H17C119.9
C1B—C7B—H7BB108.7C18C—C17C—H17C119.9
C8B—C7B—H7BB108.7C19C—C18C—C17C120.7 (4)
H7BA—C7B—H7BB107.6C19C—C18C—H18C119.7
O1B—C8B—N1B123.5 (3)C17C—C18C—H18C119.7
O1B—C8B—C7B122.9 (3)C18C—C19C—C14C118.5 (3)
N1B—C8B—C7B113.6 (2)C18C—C19C—H19C120.7
C10B—C9B—N1B129.9 (3)C14C—C19C—H19C120.7
C10B—C9B—C13B108.5 (2)
C10A—N2A—N3A—C13A7.7 (3)N1B—C9B—C10B—C11B5.7 (5)
C12A—N2A—N3A—C13A142.5 (2)C13B—C9B—C10B—C11B176.5 (3)
C10A—N2A—N3A—C14A165.7 (2)N3B—N2B—C10B—C9B6.1 (3)
C12A—N2A—N3A—C14A59.5 (3)C12B—N2B—C10B—C9B140.2 (3)
C6A—C1A—C2A—C3A0.3 (5)N3B—N2B—C10B—C11B173.2 (2)
C7A—C1A—C2A—C3A177.4 (3)C12B—N2B—C10B—C11B39.0 (4)
C1A—C2A—C3A—C4A1.4 (5)N2B—N3B—C13B—O2B172.6 (2)
C1A—C2A—C3A—Cl1A178.2 (3)C14B—N3B—C13B—O2B16.1 (4)
C2A—C3A—C4A—C5A1.0 (5)N2B—N3B—C13B—C9B5.7 (3)
Cl1A—C3A—C4A—C5A178.6 (3)C14B—N3B—C13B—C9B162.2 (2)
C2A—C3A—C4A—Cl2A178.5 (3)C10B—C9B—C13B—O2B176.3 (3)
Cl1A—C3A—C4A—Cl2A1.9 (5)N1B—C9B—C13B—O2B1.7 (4)
C3A—C4A—C5A—C6A0.9 (6)C10B—C9B—C13B—N3B1.9 (3)
Cl2A—C4A—C5A—C6A179.5 (3)N1B—C9B—C13B—N3B179.9 (2)
C4A—C5A—C6A—C1A2.6 (6)C13B—N3B—C14B—C15B117.5 (3)
C2A—C1A—C6A—C5A2.2 (5)N2B—N3B—C14B—C15B36.4 (4)
C7A—C1A—C6A—C5A175.4 (3)C13B—N3B—C14B—C19B61.1 (4)
C2A—C1A—C7A—C8A56.3 (4)N2B—N3B—C14B—C19B145.0 (3)
C6A—C1A—C7A—C8A126.1 (3)C19B—C14B—C15B—C16B1.7 (5)
C9A—N1A—C8A—O1A5.1 (4)N3B—C14B—C15B—C16B176.8 (3)
C9A—N1A—C8A—C7A176.8 (3)C14B—C15B—C16B—C17B0.0 (6)
C1A—C7A—C8A—O1A26.4 (5)C15B—C16B—C17B—C18B1.6 (6)
C1A—C7A—C8A—N1A155.4 (3)C16B—C17B—C18B—C19B1.6 (6)
C8A—N1A—C9A—C10A59.5 (4)C17B—C18B—C19B—C14B0.1 (5)
C8A—N1A—C9A—C13A123.7 (3)C15B—C14B—C19B—C18B1.8 (5)
N1A—C9A—C10A—N2A175.2 (3)N3B—C14B—C19B—C18B176.8 (3)
C13A—C9A—C10A—N2A2.0 (3)C10C—N2C—N3C—C13C6.7 (3)
N1A—C9A—C10A—C11A4.9 (5)C12C—N2C—N3C—C13C139.3 (2)
C13A—C9A—C10A—C11A178.0 (3)C10C—N2C—N3C—C14C166.5 (2)
N3A—N2A—C10A—C9A5.9 (3)C12C—N2C—N3C—C14C60.9 (3)
C12A—N2A—C10A—C9A137.2 (3)C6C—C1C—C2C—C3C0.4 (5)
N3A—N2A—C10A—C11A174.1 (2)C7C—C1C—C2C—C3C179.8 (3)
C12A—N2A—C10A—C11A42.7 (4)C1C—C2C—C3C—C4C0.2 (5)
N2A—N3A—C13A—O2A172.2 (2)C1C—C2C—C3C—Cl1C179.1 (3)
C14A—N3A—C13A—O2A15.3 (4)C2C—C3C—C4C—C5C0.8 (5)
N2A—N3A—C13A—C9A6.4 (3)Cl1C—C3C—C4C—C5C179.9 (3)
C14A—N3A—C13A—C9A163.3 (2)C2C—C3C—C4C—Cl2C179.5 (3)
C10A—C9A—C13A—O2A175.8 (3)Cl1C—C3C—C4C—Cl2C1.2 (4)
N1A—C9A—C13A—O2A1.6 (5)C3C—C4C—C5C—C6C1.7 (5)
C10A—C9A—C13A—N3A2.8 (3)Cl2C—C4C—C5C—C6C179.6 (3)
N1A—C9A—C13A—N3A179.8 (2)C2C—C1C—C6C—C5C0.5 (5)
C13A—N3A—C14A—C15A122.7 (3)C7C—C1C—C6C—C5C178.9 (3)
N2A—N3A—C14A—C15A31.7 (4)C4C—C5C—C6C—C1C1.5 (6)
C13A—N3A—C14A—C19A56.1 (4)C6C—C1C—C7C—C8C117.2 (3)
N2A—N3A—C14A—C19A149.5 (3)C2C—C1C—C7C—C8C63.4 (4)
C19A—C14A—C15A—C16A0.1 (5)C9C—N1C—C8C—O1C8.7 (4)
N3A—C14A—C15A—C16A178.9 (3)C9C—N1C—C8C—C7C169.1 (3)
C14A—C15A—C16A—C17A0.9 (5)C1C—C7C—C8C—O1C26.7 (4)
C15A—C16A—C17A—C18A1.4 (6)C1C—C7C—C8C—N1C155.5 (3)
C16A—C17A—C18A—C19A1.0 (6)C8C—N1C—C9C—C10C58.1 (4)
C15A—C14A—C19A—C18A0.3 (5)C8C—N1C—C9C—C13C122.4 (3)
N3A—C14A—C19A—C18A178.6 (3)N1C—C9C—C10C—N2C178.0 (2)
C17A—C18A—C19A—C14A0.2 (5)C13C—C9C—C10C—N2C1.6 (3)
C10B—N2B—N3B—C13B7.4 (3)N1C—C9C—C10C—C11C1.5 (5)
C12B—N2B—N3B—C13B145.0 (2)C13C—C9C—C10C—C11C178.9 (3)
C10B—N2B—N3B—C14B164.4 (2)N3C—N2C—C10C—C9C5.0 (3)
C12B—N2B—N3B—C14B58.0 (3)C12C—N2C—C10C—C9C134.8 (3)
C6B—C1B—C2B—C3B0.5 (5)N3C—N2C—C10C—C11C175.4 (2)
C7B—C1B—C2B—C3B179.8 (3)C12C—N2C—C10C—C11C45.6 (4)
C1B—C2B—C3B—C4B0.2 (5)N2C—N3C—C13C—O2C173.1 (2)
C1B—C2B—C3B—Cl1B177.6 (3)C14C—N3C—C13C—O2C15.1 (4)
C2B—C3B—C4B—C5B0.0 (5)N2C—N3C—C13C—C9C5.7 (3)
Cl1B—C3B—C4B—C5B177.8 (3)C14C—N3C—C13C—C9C163.7 (3)
C2B—C3B—C4B—Cl2B179.2 (3)C10C—C9C—C13C—O2C176.2 (3)
Cl1B—C3B—C4B—Cl2B1.3 (4)N1C—C9C—C13C—O2C3.4 (5)
C3B—C4B—C5B—C6B0.9 (5)C10C—C9C—C13C—N3C2.5 (3)
Cl2B—C4B—C5B—C6B178.2 (3)N1C—C9C—C13C—N3C177.9 (2)
C4B—C5B—C6B—C1B1.6 (6)C13C—N3C—C14C—C15C125.5 (3)
C2B—C1B—C6B—C5B1.4 (5)N2C—N3C—C14C—C15C30.7 (4)
C7B—C1B—C6B—C5B179.3 (3)C13C—N3C—C14C—C19C54.1 (4)
C2B—C1B—C7B—C8B60.7 (4)N2C—N3C—C14C—C19C149.7 (3)
C6B—C1B—C7B—C8B118.6 (3)C19C—C14C—C15C—C16C0.8 (5)
C9B—N1B—C8B—O1B10.9 (5)N3C—C14C—C15C—C16C179.6 (3)
C9B—N1B—C8B—C7B166.8 (3)C14C—C15C—C16C—C17C0.7 (6)
C1B—C7B—C8B—O1B29.8 (5)C15C—C16C—C17C—C18C0.1 (7)
C1B—C7B—C8B—N1B152.5 (3)C16C—C17C—C18C—C19C0.7 (7)
C8B—N1B—C9B—C10B60.3 (4)C17C—C18C—C19C—C14C0.6 (5)
C8B—N1B—C9B—C13B122.2 (3)C15C—C14C—C19C—C18C0.2 (5)
N1B—C9B—C10B—N2B175.1 (3)N3C—C14C—C19C—C18C179.8 (3)
C13B—C9B—C10B—N2B2.7 (3)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N1A—H1AA···O2Ai0.881.982.820 (3)159
N1B—H1BA···O2C0.882.012.849 (3)159
N1C—H1CA···O2B0.881.962.795 (3)158
C11A—H11C···O2Bii0.982.393.344 (4)163
C11C—H11H···O2Aiii0.982.453.377 (4)158
C12C—H12G···O2Aiii0.982.443.186 (4)133
C12C—H12H···O1Biii0.982.513.178 (4)125
C12A—H12A···O2Bii0.982.503.273 (4)136
C11B—H11F···O2Civ0.982.423.364 (4)163
C12B—H12D···O2Civ0.982.463.282 (4)142
C17B—H17B···Cl1Bv0.952.893.705 (4)144
Symmetry codes: (i) x+1, y+1, z+2; (ii) x+1, y1/2, z+3/2; (iii) x, y+3/2, z1/2; (iv) x+1, y+1, z+1; (v) x+1, y, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N1A—H1AA···O2Ai0.881.982.820 (3)159.3
N1B—H1BA···O2C0.882.012.849 (3)158.8
N1C—H1CA···O2B0.881.962.795 (3)157.6
C11A—H11C···O2Bii0.982.393.344 (4)163.4
C11C—H11H···O2Aiii0.982.453.377 (4)158.1
C12C—H12G···O2Aiii0.982.443.186 (4)132.6
C12C—H12H···O1Biii0.982.513.178 (4)125.1
C12A—H12A···O2Bii0.982.503.273 (4)136.1
C11B—H11F···O2Civ0.982.423.364 (4)162.7
C12B—H12D···O2Civ0.982.463.282 (4)141.6
C17B—H17B···Cl1Bv0.952.893.705 (4)144.1
Symmetry codes: (i) x+1, y+1, z+2; (ii) x+1, y1/2, z+3/2; (iii) x, y+3/2, z1/2; (iv) x+1, y+1, z+1; (v) x+1, y, z.
Acknowledgements top

RJB acknowledges the NSF–MRI program (grant No. CHE-0619278) for funds to purchase the diffractometer.

references
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