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Acta Cryst. (2013). E69, o325
[ doi:10.1107/S1600536813002973 ]

(±)-(4aR,5R,8S,8aR)-8-(tert-Butyldimethylsilyloxy)-2,5,8a-trimethyl-4a,5,8,8a-tetrahydronaphthalene-1,4-dione

F. N. Delling, J. Zukerman-Schpector, T. J. Brocksom, U. Brocksom, F. G. Finelli and E. R. T. Tiekink

Abstract: In the title compound, C19H30O3Si, both rings adopt a half-boat conformation. Overall, the molecule approximates a U-shape as the cyclo-2-ene-1,4-dione and butyldimethylsilyloxy substituents lie to the same side of the central cyclohexene ring; the methyl substituent lies to the other side of the molecule. In the crystal, linear supramolecular chains along the b axis are sustained by C-H...O interactions.


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