Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 3 (March 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m172    [ doi:10.1107/S1600536813004091 ]


Z.-Y. Xiong, L. Li, X.-J. Zhao and H.-M. Chen

Abstract: In the title compound, [Mn(C4H3N2O2)2(H2O)2], the MnII ion is located on a twofold rotation axis and displays a distorted octa­hedral coordination environment, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in axial positions. In the crystal, O-H...O and N-H...O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. [pi]-[pi] stacking inter­actions between the imidazole rings [centroid-centroid distances = 3.5188 (15) and 3.6687 (15) Å] further stabilize the structure.

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