Received 14 January 2013
aDepartment of Chemistry, Faculty of Science, Prince of Songkla University, Hat-Yai, Songkhla 90112, Thailand,bFaculty of Traditional Thai Medicine, Prince of Songkla University, Hat-Yai, Songkhla 90112, Thailand,cX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia, and dDepartment of Pharmaceutical Chemistry, College of Pharmacy, King Saud University, PO Box 2457, Riyadh 11451, Saudi Arabia
Correspondence e-mail: firstname.lastname@example.org
In the title hydrated salt, C19H25N2+·I-·H2O, the 4-(diethylamino)phenyl unit of the cation is disordered over two positions in a 0.847 (3):0.153 (3) ratio. The cation is twisted, with dihedral angles between the pyridinium and benzene rings of 11.25 (13) and 10.7 (8)° for the major and minor components, respectively. In the crystal, the three components are linked into a centrosymmetric 2:2:2 unit by O-HI and C-HO hydrogen bonds. - interactions with centroid-centroid distances of 3.5065 (7)-3.790 (9) Å are also present.
For background to and applications of aminostyrylpyridinium compounds, see: Chanawanno et al. (2010); Larnbert et al. (1996). For related structures, see: Fun et al. (2011a,b); Kaewmanee et al. (2010). For bond-length data, see: Allen et al. (1987).
Data collection: APEX2 (Bruker, 2009); cell refinement: SAINT (Bruker, 2009); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 2009).
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: IS5238 ).
SC, NB and NK thank Prince of Songkla University for a research grant. The authors also thank the Malaysian Government and Universiti Sains Malaysia for APEX DE2012 grant No. 1002/PFIZIK/910323.
Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G. & Taylor, R. (1987). J. Chem. Soc. Perkin Trans. 2, pp. S1-19.
Bruker (2009). APEX2, SAINT and SADABS, Bruker AXS Inc., Madison, Wisconsin, USA.
Chanawanno, K., Chantrapromma, S., Anantapong, T., Kanjana-Opas, A. & Fun, H.-K. (2010). Eur. J. Med. Chem. 45, 4199-4208.
Fun, H.-K., Kaewmanee, N., Chanawanno, K. & Chantrapromma, S. (2011a). Acta Cryst. E67, o593-o594.
Fun, H.-K., Kaewmanee, N., Chanawanno, K., Karalai, C. & Chantrapromma, S. (2011b). Acta Cryst. E67, o2488-o2489.
Kaewmanee, N., Chanawanno, K., Chantrapromma, S. & Fun, H.-K. (2010). Acta Cryst. E66, o2639-o2640.
Larnbert, C., Mease, R. C., Amen, L., Le, T., Sabet, H. & McAfee, J. G. (1996). Nucl. Med. Biol., 23, 417-427.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Spek, A. L. (2009). Acta Cryst. D65, 148-155.