Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 3 (March 2013)


metal-organic compounds



ng5315 scheme

Acta Cryst. (2013). E69, m143    [ doi:10.1107/S1600536813003462 ]

Tris[dimethyl (benzoylamido)phosphato-[kappa]2O,O'](1,10-phenanthroline-[kappa]2N,N')neodymium(III)

N. S. Kariaka, V. A. Trush, V. V. Medviediev, T. Y. Sliva and V. M. Amirkhanov

Abstract: In both independent molecules of the title compound, [Nd(C9H11NO4P)3(C12H8N2)], the NdIII atom is coordinated by six O atoms belonging to three phosphoryl ligands and two N atoms of 1,10-phenanthroline in a dodecahedral geometry. In the phosphoryl ligands, the benzene rings are twisted with respect to the planes of the sp2-hybridized C atoms of the chelate rings by 12.1 (1)-24.7 (1)°.


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