Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 3 (March 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m137-m138    [ doi:10.1107/S1600536813003152 ]


R. Venkatraman, K. D. Ruddock, H. S. Das, M. A. Hossain and F. R. Fronczek

Abstract: The title compound, [Ag(C9H13N5S)Cl(C18H15P)2], crystallizes with four independent mol­ecules in the asymmetric unit, in each of which the Ag atom is in a distorted tetra­hedral coordination, defined by the chloride ligand, the S atom of the neutral ligand and two P atoms derived from the triphenyl phosphine ligands. The thio­semicarbazone acts as a monodentate ligand through its thione S atom. An intra­molecular N-H...Cl hydrogen bond occurs in two of the independent mol­ecules. In the crystal, the mol­ecules are assembled through N-H...Cl hydrogen bonds, forming chains along [101].

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