Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 3 (March 2013)


metal-organic compounds



rk2386 scheme

Acta Cryst. (2013). E69, m137-m138    [ doi:10.1107/S1600536813003152 ]

Chlorido{4-ethyl-1-[1-(pyrazin-2-yl)ethylidene]thiosemicabazidato-[kappa]S}bis(triphenylphosphane-[kappa]P)silver(I)

R. Venkatraman, K. D. Ruddock, H. S. Das, M. A. Hossain and F. R. Fronczek

Abstract: The title compound, [Ag(C9H13N5S)Cl(C18H15P)2], crystallizes with four independent molecules in the asymmetric unit, in each of which the Ag atom is in a distorted tetrahedral coordination, defined by the chloride ligand, the S atom of the neutral ligand and two P atoms derived from the triphenyl phosphine ligands. The thiosemicarbazone acts as a monodentate ligand through its thione S atom. An intramolecular N-H...Cl hydrogen bond occurs in two of the independent molecules. In the crystal, the molecules are assembled through N-H...Cl hydrogen bonds, forming chains along [101].


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