(1RS,2RS)-4,4′-(1-Aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium tetra­chlorido­platinate(II) chloride

Campos-Gaxiola, J.J.; Almaral-Sanchez, J.L.; Cruz-Enriquez, A.; Höpfl, H.; Parra-Hake, M.

doi:10.1107/S160053681300425X

Volume 69
Part 3
Pages m157-m158
March 2013

Received 5 February 2013
Accepted 12 February 2013
Online 20 February 2013

Key indicators
Single-crystal X-ray study
T = 100 K
Mean (C-C) = 0.010 Å
R = 0.038
wR = 0.091
Data-to-parameter ratio = 13.4
Details

(1RS,2RS)-4,4'-(1-Azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium tetrachloridoplatinate(II) chloride

José J. Campos-Gaxiola,^a ^* Jorge L. Almaral-Sanchez,^a Adriana Cruz-Enríquez,^a Herbert Höpfl ^b and Miguel Parra-Hake ^c

^aFacultad de Ingenieria Mochis, Universidad Autónoma de Sinaloa, Fuente Poseidón y Prol. A. Flores S/N, CP 81223, C.U. Los Mochis, Sinaloa, México,^bCentro de Investigaciones Quimicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, CP 62210, Cuernavaca, Morelos, México, and ^cCentro de Graduados e Investigación en Química del Instituto Tecnologico de Tijuana, Blvd. Industrial S/N, Col. Otay, CP 22500, Tijuana, B.C., México
Correspondence e-mail: gaxiolajose@yahoo.com.mx

The title compound, (C₁₂H₁₆N₃O)[PtCl₄]Cl, consists of a 4,4'-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium trication, a square-planar tetrachloridoplatinate(II) dianion and a chloride ion. In the cation, the pyridinium rings attached to the central 1-azaniumyl-2-hydroxyethane fragment have an anti conformation, as indicated by the central C-C-C-C torsion angle of -166.5 (6)°, and they are inclined to one another by 63.5 (4)°. In the crystal, the cations and anions are linked through N-HCl and O-HCl hydrogen bonds. There are also [pi] - [pi] contacts [centroid-centroid distances = 3.671 (4) and 3.851 (4) Å] and a number of C-HCl interactions present, consolidating the formation of a three-dimensional supramolecular structure.

Related literature

For potential applications of organic-inorganic hybrid materials with magnetic, optical and electrical properties, see: Yao et al. (2010); Sanchez et al. (2011); Pardo et al. (2011); Piecha et al. (2012). For related tetrachloroplatinate(II) compounds, see: Fusi et al. (2012); Adarsh et al. (2010); Campos-Gaxiola et al. (2010); Adams et al. (2005). For the synthesis of the title ligand, see: Campos-Gaxiola et al. (2012).

Experimental

Crystal data

(C₁₂H₁₆N₃O)[PtCl₄]Cl
M_r = 590.62
Triclinic, $[P \overline 1]$
a = 7.636 (2) Å
b = 8.082 (2) Å
c = 14.599 (4) Å
= 88.689 (4)°
= 84.240 (4)°
= 70.148 (4)°
V = 843.1 (4) Å³
Z = 2
Mo K radiation
= 9.12 mm^-1
T = 100 K
0.50 × 0.26 × 0.12 mm

Data collection

Bruker SMART CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) T_min = 0.092, T_max = 0.408
5093 measured reflections
2911 independent reflections
2726 reflections with I > 2(I)
R_int = 0.043

Refinement

R[F² > 2(F²)] = 0.038
wR(F²) = 0.091
S = 1.05
2911 reflections
217 parameters
6 restraints
H atoms treated by a mixture of independent and constrained refinement
_max = 2.34 e Å^-3
_min = -1.98 e Å^-3

Table 1
Hydrogen-bond geometry (Å, °)

D-HA	D-H	HA	DA	D-HA
O1-H1'Cl1ⁱ	0.84 (6)	2.49 (7)	3.250 (6)	152 (6)
N1-H1ACl5ⁱⁱ	0.86 (7)	2.32 (6)	3.148 (6)	162 (7)
N1-H1BCl5ⁱⁱⁱ	0.86 (5)	2.30 (6)	3.097 (7)	154 (7)
N1-H1CCl2	0.86 (5)	2.50 (5)	3.214 (6)	141 (6)
N1-H1CCl3	0.86 (5)	2.58 (7)	3.242 (6)	134 (6)
N2-H2'Cl5^iv	0.84 (4)	2.45 (7)	3.088 (6)	134 (7)
N2-H2'Cl5^v	0.84 (4)	2.69 (6)	3.272 (6)	128 (7)
N3-H3'Cl1^vi	0.84 (6)	2.50 (6)	3.275 (6)	155 (6)
N3-H3'Cl4^vi	0.84 (6)	2.72 (7)	3.286 (7)	127 (7)
C1-H1Cl1^vii	0.98	2.71	3.660 (8)	163
C5-H5Cl3ⁱⁱⁱ	0.93	2.71	3.604 (8)	162
C10-H10Cl3ⁱ	0.93	2.73	3.459 (8)	136
C10-H10Cl5^v	0.93	2.74	3.308 (7)	120
C11-H11Cl2^viii	0.93	2.64	3.449 (8)	145
Symmetry codes: (i) x-1, y+1, z; (ii) x, y, z-1; (iii) -x+1, -y+1, -z+1; (iv) x, y+1, z-1; (v) -x, -y+2, -z+1; (vi) -x+1, -y, -z+1; (vii) x, y+1, z; (viii) -x+1, -y+1, -z.

Data collection: SMART (Bruker, 2000); cell refinement: SAINT-Plus-NT (Bruker 2001); data reduction: SAINT-Plus-NT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012) and Mercury (Macrae et al., 2008); software used to prepare material for publication: publCIF (Westrip, 2010).

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: SU2560 ).

Acknowledgements

This work was supported financially by the Universidad Autónoma de Sinaloa (PROFAPI 2012/032).

References

Adams, C. J., Paul, C. C., Orpen, A. G., Podesta, T. J. & Salt, B. (2005). Chem. Commun. pp. 2457-2458.
Adarsh, N. N., Krishna Kumar, D. & Dastidar, P. (2010). Acta Cryst. E66, m270.
Bruker (2000). SMART. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2001). SAINT-Plus-NT. Bruker AXS Inc., Madison, Wisconsin, USA.
Campos-Gaxiola, J. J., Höpfl, H., Aguirre, G. & Parra-Hake, M. (2012). Acta Cryst. E68, o1873.
Campos-Gaxiola, J. J., Vega-Paz, A., Román-Bravo, P., Höpfl, H. & Sánchez-Vázquez, M. (2010). Cryst. Growth Des. 10, 3182-3190.
Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.
Fusi, V., Giorgi, L., Macedi, E., Paoli, P. & Rossi, P. (2012). Acta Cryst. E68, m1323-m1324.
Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J. & Wood, P. A. (2008). J. Appl. Cryst. 41, 466-470.
Pardo, R., Zayat, M. & Levy, D. (2011). Chem. Soc. Rev. 40, 672-687.
Piecha, A., Bialoríska, A. & Jakubas, R. (2012). J. Mater. Chem. 22, 333-336.
Sanchez, C., Belleville, P., Popall, M. & Lionel, N. (2011). Chem. Soc. Rev. 40, 696-753.
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.
Yao, H. B., Gao, M. R. & Yu, S. H. (2010). Nanoscale, 2, 323-334.

metal-organic compounds