Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 3 (March 2013)

organic compounds

Acta Cryst. (2013). E69, o391    [ doi:10.1107/S1600536813004236 ]

2-[N-(4-Meth­oxy­phen­yl)acetamido]-1,3-thia­zol-4-yl acetate

V. Horishny, R. Lesyk and A. K. Gzella

Abstract: The structural analysis of the title compound, C14H14N2O4S, particularly the presence of an acetyl group at the exocyclic N atom and the C(H)-C(O2CMe)-N acet­oxy group in the thia­zole ring, may indicate that one of the starting materials, i.e. 2-(4-meth­oxy­anilino)-1,3-thia­zol-4(5H)-one, exists in the reaction mixture, at least partially, as a tautomer with an exocyclic amine N atom and an enol group. The acet­oxy and acetyl groups deviate from the thia­zole plane by 69.17 (6) and 7.25 (19)°, respectively. The thia­zole and benzene rings form a dihedral angle of 73.50 (4)°. In the crystal, centrosymmetrically related mol­ecules are connected into dimeric aggregates via C-H...O inter­actions.

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