Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 3 (March 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m165-m166    [ doi:10.1107/S1600536813004534 ]

Bis{2-[(guanidinoimino)­meth­yl]phenolato-[kappa]3N,N',O}cobalt(III) chloride hemihydrate

E. A. Buvaylo, V. N. Kokozay, O. Y. Vassilyeva and B. W. Skelton

Abstract: The title compound, [Co(C8H9N4O)2]Cl·0.5H2O, is a solvatomorph of the corresponding trihydrate. Unlike in the structure of the latter compound, there are two different cations in the asymmetric unit of the title compound. The ligand mol­ecules are deprotonated at the phenol O atom and octa­hedrally coordinate the CoIII atoms through the azomethine N and phenolate O atoms in a mer configuration. In the crystal, the cations, chloride ions and lattice water mol­ecules are linked by N-H...O, N-H...Cl, O-H...Cl and O-H...O inter­actions, forming a two-dimensional network parallel to (10-1).

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