Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 3 (March 2013)


metal-organic compounds



xu5676 scheme

Acta Cryst. (2013). E69, m169    [ doi:10.1107/S1600536813004686 ]

Bis(azido-[kappa]N)bis[4-(dimethylamino)pyridine-[kappa]N]zinc

F. Guenifa, N. Hadjadj, O. Zeghouan, L. Bendjeddou and H. Merazig

Abstract: In the title complex, [Zn(N3)2(C7H10N2)2], the ZnII atom is coordinated by two N atoms from two 4-(dimethylamino)pyridine (DMAP) ligands and by two N atoms from two azide anions in a distorted tetrahedral coordination geometry. In the crystal, weak C-H...N hydrogen bonds between the DMAP and azide ligands link these discrete complex molecules into a three-dimensional supramolecular network.


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