Acta Cryst. (2013). E69, m167 [ doi:10.1107/S1600536813004674 ]
Abstract: The asymmetric unit of the title compound, [Sb(C6H5)3(C10H9O3)2]·C6H6, contains one organometallic molecule and one benzene molecule that is disordered over two sets of sites with an occupancy ratio of 0.556 (15):0.444 (15). The SbV atom is in a distorted trigonal-bipyramidal environment with the carboxylate O atoms in axial positions and phenyl C atoms in the equatorial plane. As a result of additional SbO interactions, one of the C-Sb-C angles is widened to 140.19 (6)°.
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