Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 3 (March 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m154-m155    [ doi:10.1107/S1600536813003772 ]


K.-L. Zhong

Abstract: The title compound, [Ni(SO4)(C10H8N2)(C2H6O2)(H2O)]n, contains two crystallographically unique NiII atoms, each lying on a twofold rotation axis and having a slightly distorted octa­hedral environment. It is isotypic with the previously reported CuII analog [Zhong et al. (2011). Acta Cryst. C67, m62-m64]. One NiII atom is coordinated by two N atoms from two bridging 4,4'-bipyridine (4,4'-bipy) ligands, two O atoms from two sulfate ions and two aqua O atoms. The second NiII atom is surrounded by two N atoms from 4,4'-bipy ligands and four O atoms, two from bridging sulfate ions and from two ethane-1,2-diol ligands. The sulfate anion acts as a bridging ligand, linking adjacent NiII atoms, leading to the formation of linear ...Ni1-Ni2-Ni1-Ni2... chains along the a-axis direction. Adjacent chains are further bridged by 4,4'-bipy ligands, resulting in a two-dimensional layered polymer parallel to (001). In the crystal, the polymeric layers are linked by extensive O-H...O hydrogen-bonding inter­actions involving the O atoms of the water mol­ecules and the ethane-1,2-diol mol­ecules, resulting in a three-dimensional supra­molecular network.

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813003772/zq2195sup0.html ]
Supplementary materials


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster