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Volume 69 
Part 3 
Pages m154-m155  
March 2013  

Received 22 January 2013
Accepted 7 February 2013
Online 16 February 2013

Key indicators
Single-crystal X-ray study
T = 223 K
Mean [sigma](C-C) = 0.003 Å
R = 0.033
wR = 0.086
Data-to-parameter ratio = 16.0
Details
Open access

Poly[aqua([mu]2-4,4'-bipyridine-[kappa]2N:N')(ethane-1,2-diol-[kappa]O)([mu]2-sulfato-[kappa]2O:O')nickel(II)]

aDepartment of Applied Chemistry, Nanjing College of Chemical Technology, Nanjing 210048, People's Republic of China
Correspondence e-mail: zklong@tom.com

The title compound, [Ni(SO4)(C10H8N2)(C2H6O2)(H2O)]n, contains two crystallographically unique NiII atoms, each lying on a twofold rotation axis and having a slightly distorted octahedral environment. It is isotypic with the previously reported CuII analog [Zhong et al. (2011[Zhong, K.-L., Chen, L. & Chen, L. (2011). Acta Cryst. C67, m62-m64.]). Acta Cryst. C67, m62-m64]. One NiII atom is coordinated by two N atoms from two bridging 4,4'-bipyridine (4,4'-bipy) ligands, two O atoms from two sulfate ions and two aqua O atoms. The second NiII atom is surrounded by two N atoms from 4,4'-bipy ligands and four O atoms, two from bridging sulfate ions and from two ethane-1,2-diol ligands. The sulfate anion acts as a bridging ligand, linking adjacent NiII atoms, leading to the formation of linear ...Ni1-Ni2-Ni1-Ni2... chains along the a-axis direction. Adjacent chains are further bridged by 4,4'-bipy ligands, resulting in a two-dimensional layered polymer parallel to (001). In the crystal, the polymeric layers are linked by extensive O-H...O hydrogen-bonding interactions involving the O atoms of the water molecules and the ethane-1,2-diol molecules, resulting in a three-dimensional supramolecular network.

Related literature

For Ni-(4,4'-bipy) complexes with perchlorate, citraconate or phthalate anions and a water molecule as a second ligand, see: Yang et al. (2003[Yang, S.-Y., Long, L.-S., Huang, R.-B., Zheng, L.-S. & Ng, S. W. (2003). Acta Cryst. E59, m507-m509.]); Kopf et al. (2005[Kopf, A. L., Maggard, P. A., Stern, C. L. & Poeppelmeier, K. R. (2005). Acta Cryst. C61, m165-m168.]); Wang et al. (2006[Wang, X.-L., Qin, C. & Wang, E.-B. (2006). Cryst. Growth Des. 6, 439-443.]). For an isotypic structure, see: Zhong et al. (2011[Zhong, K.-L., Chen, L. & Chen, L. (2011). Acta Cryst. C67, m62-m64.]). For background to coordination polymers, see: Dietzel et al. (2005[Dietzel, P. D. C., Morita, Y., Blom, R. & Fjellvåg, H. (2005). Angew. Chem. Int. Ed. 44, 1483-1492.]); Robin & Fromm (2006[Robin, A. Y. & Fromm, K. M. (2006). Coord. Chem. Rev. 250, 2127-2157.]); Sarma et al. (2009[Sarma, D., Ramanujachary, K. V., Lofland, S. E., Magdaleno, T. & Natarajan, S. (2009). Inorg. Chem. 48, 11660-11676.]); Zhang et al. (2010[Zhang, L.-P., Ma, J.-F., Yang, J., Pang, Y.-Y. & Ma, J.-C. (2010). Inorg. Chem. 49, 1535-1550.]).

[Scheme 1]

Experimental

Crystal data
  • [Ni(SO4)(C10H8N2)(C2H6O2)(H2O)]

  • Mr = 391.04

  • Monoclinic, C 2/c

  • a = 11.022 (2) Å

  • b = 22.606 (5) Å

  • c = 12.123 (2) Å

  • [beta] = 95.65 (3)°

  • V = 3005.9 (10) Å3

  • Z = 8

  • Mo K[alpha] radiation

  • [mu] = 1.47 mm-1

  • T = 223 K

  • 0.40 × 0.35 × 0.10 mm

Data collection
  • Rigaku Mercury CCD diffractometer

  • Absorption correction: multi-scan (REQAB; Jacobson, 1998[Jacobson, R. (1998). REQAB. Molecular Structure Corporation, The Woodlands, Texas, USA.]) Tmin = 0.743, Tmax = 1.000

  • 8555 measured reflections

  • 3420 independent reflections

  • 2885 reflections with I > 2[sigma](I)

  • Rint = 0.024

Refinement
  • R[F2 > 2[sigma](F2)] = 0.033

  • wR(F2) = 0.086

  • S = 1.06

  • 3420 reflections

  • 214 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.56 e Å-3

  • [Delta][rho]min = -0.41 e Å-3

Table 1
Selected bond lengths (Å)

Ni1-N2 2.072 (2)
Ni1-O1W 2.0809 (15)
Ni1-O1 2.0844 (14)
Ni1-N1 2.101 (2)
Ni2-O5 2.0591 (15)
Ni2-O2 2.0817 (15)
Ni2-N4 2.096 (2)
Ni2-N3 2.101 (2)

Table 2
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O6-H6A...O4i 0.82 1.89 2.694 (2) 165
O5-H5B...O1 0.82 1.82 2.599 (2) 158
O1W-H1WA...O6 0.85 1.86 2.693 (2) 167
O1W-H1WB...O3ii 0.85 1.91 2.718 (2) 157
Symmetry codes: (i) [x, -y+1, z+{\script{1\over 2}}]; (ii) [-x+1, y, -z+{\script{1\over 2}}].

Data collection: CrystalClear (Rigaku, 2007[Rigaku (2007). CrystalClear. Rigaku Corporation, Tokyo, Japan.]); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: XP in SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: ZQ2195 ).


Acknowledgements

This work was supported by the Scientific Research Foundation of Nanjing College of Chemical Technology (grant No. NHKY-2013-10).

References

Dietzel, P. D. C., Morita, Y., Blom, R. & Fjellvåg, H. (2005). Angew. Chem. Int. Ed. 44, 1483-1492.  [ISI] [CSD] [CrossRef]
Jacobson, R. (1998). REQAB. Molecular Structure Corporation, The Woodlands, Texas, USA.
Kopf, A. L., Maggard, P. A., Stern, C. L. & Poeppelmeier, K. R. (2005). Acta Cryst. C61, m165-m168.  [CSD] [CrossRef] [details]
Rigaku (2007). CrystalClear. Rigaku Corporation, Tokyo, Japan.
Robin, A. Y. & Fromm, K. M. (2006). Coord. Chem. Rev. 250, 2127-2157.  [ISI] [CrossRef] [ChemPort]
Sarma, D., Ramanujachary, K. V., Lofland, S. E., Magdaleno, T. & Natarajan, S. (2009). Inorg. Chem. 48, 11660-11676.  [ISI] [CSD] [CrossRef] [PubMed] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Wang, X.-L., Qin, C. & Wang, E.-B. (2006). Cryst. Growth Des. 6, 439-443.  [CSD] [CrossRef] [ChemPort]
Yang, S.-Y., Long, L.-S., Huang, R.-B., Zheng, L.-S. & Ng, S. W. (2003). Acta Cryst. E59, m507-m509.  [CSD] [CrossRef] [details]
Zhang, L.-P., Ma, J.-F., Yang, J., Pang, Y.-Y. & Ma, J.-C. (2010). Inorg. Chem. 49, 1535-1550.  [ISI] [CSD] [CrossRef] [ChemPort] [PubMed]
Zhong, K.-L., Chen, L. & Chen, L. (2011). Acta Cryst. C67, m62-m64.  [CSD] [CrossRef] [details]


Acta Cryst (2013). E69, m154-m155   [ doi:10.1107/S1600536813003772 ]

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