Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)

organic compounds

Acta Cryst. (2013). E69, o512    [ doi:10.1107/S1600536813005515 ]

[2-Acet­oxy-3-(naphthalen-1-yl­oxy)prop­yl](propan-2-yl)aza­nium chloride monohydrate

Y.-Y. Liu, G.-H. Xu, Z.-J. Li, H.-Y. Xu and C.-Q. Gu

Abstract: The title compound, C18H24NO3+·Cl-·H2O, was synthesized by the reaction of propranolol hydro­chloride with acetyl chloride in chloro­form followed by slow evaporation in air. In the cation, the dihedral angle between the planes of the naphthalene ring system and the acetate group is 71.1 (2)°. An intra­molecular N-H...O hydrogen bond results in the formation of a non-planar pseudo-ring, with the ether O and the H atom displaced by -1.328 (2) and 0.65 Å, respectively, from the plane of the other ring atoms. The cation and anion are linked by an N-H...Cl hydrogen bond. The water molecule is linked to a methyl H atom by C-H...O hydrogen bond.

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