Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m222    [ doi:10.1107/S1600536813007022 ]

Bis{2,2'-[methyl­aza­nediylbis(methyl­ene)]bis­(4,6-dimethyl­phenolato)-[kappa]3O,N,O'}titanium(IV) toluene sesquisolvate

Y. Chung and Y. Kim

Abstract: The title compound, [Ti(C19H23NO2)2]·1.5C7H8, crystallizes with one titanium complex mol­ecule per asymmetric unit together with one and a half toluene mol­ecules. The TiIV atom is coordinated by two fully deprotonated O,N,O'-tridentate phen­oxy­amine ligands in a distorted octa­hedral environment. Within this arrangement the O atoms occupy the equatorial sites and the N atoms the axial sites. One of the toluene mol­ecules is disordered over two sets of sites in a 0.628 (18):0.372 (18) ratio.

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