Acta Cryst. (2013). E69, o487 [ doi:10.1107/S160053681300576X ]
Abstract: In the title salt, C8H10N+·H2PO4-, the cation is essentially planar (r.m.s. deviation = 0.063 Å). In the crystal, the phosphate anions form inversion R22(8) dimers via pairs of O-HO hydrogen bonds. These dimers are further linked by pairs of O-HO hydrogen bonds, also enclosing R22(8) loops, forming chains running along . The cations are bonded to the anions via N-HO hydrogen bonds and C-HO contacts.
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