Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)


metal-organic compounds



bt6894 scheme

Acta Cryst. (2013). E69, m205-m206    [ doi:10.1107/S1600536813006442 ]

cis-Chlorido(methylamine)bis(propane-1,3-diamine)cobalt(III) dichloride monohydrate

V. Maheshwaran, M. Manjunathan, K. Anbalagan, V. Thiruselvam and M. N. Ponnuswamy

Abstract: In the title compound, [CoCl(CH5N)(C3H10N2)2]Cl2·H2O, the CoIII ion has an octahedral coordination environment and is surrounded by four N atoms of two propane-1,3-diamine ligands in the equatorial plane, with another N atom of the methylamine ligand and a Cl atom occupying the axial positions. The crystal packing is stabilized by intermolecular N-H...O, N-H...Cl, and O-H...Cl interactions, generating a three-dimensional network.


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