Acta Cryst. (2013). E69, m209 [ doi:10.1107/S1600536813006703 ]
Abstract: The mononuclear title complex, [VCl2O(C3H8S)2], features a VIV=O double bond [1.5845 (15) Å] in an overall trigonal-bipyramidal coordination environment defined by two Cl- and the S atoms of two (CH3CH2)(CH3)S ligands. In the crystal, pairs of molecules form centrosymmetric dimers via C-HO hydrogen bonds between the methyl C-H group and the oxidovanadium O atom of a neighbouring molecule.
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