Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)

organic compounds

Acta Cryst. (2013). E69, o565-o566    [ doi:10.1107/S1600536813007241 ]

Ethyl 23-benzyl-8,11,14-trioxa-23,28,29-triaza­penta­cyclo­[,7.015,20.022,27]nona­cosa-2,4,6,15(20),16,18,21,26-octa­ene-26-carboxyl­ate

T. H. Hieu, L. T. Anh, A. T. Soldatenkov, V. G. Vasil'ev and V. N. Khrustalev

Abstract: The title compound, C33H35N3O5, is the product of the multicomponent condensation of 1-benzyl-4-eth­oxy­carbonyl­piperidin-3-one with 1,5-bis­(2-formyl­phen­oxy)-3-oxapentane and ammonium acetate. The mol­ecule comprises a penta­cyclic system containing the aza-14-crown-4-ether macrocycle, tetra­hydro­pyrimidine, tetra­hydro­pyridine and two benzene rings. The aza-14-crown-4-ether ring adopts a bowl conformation with a dihedral angle of 62.37 (5)° between the benzene rings. The tetra­hydro­pyrimidine ring has an envelope conformation with the chiral C atom as the flap, whereas the tetra­hydro­pyridine ring adopts a distorted chair conformation. Two amino groups are involved in intra­molecular N-H...O hydrogen bonds. In the crystal, weak C-H...O hydrogen bonds link the mol­ecules into layers parallel to the ab plane.

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