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Acta Cryst. (2013). E69, m216
[ doi:10.1107/S1600536813006107 ]

catena-Poly[[[bis(4-pyridinealdoxime-[kappa]N1)zinc]-[mu]-benzene-1,4-dicarboxylato-[kappa]2O1:O4] 4-pyridinealdoxime monosolvate]

H. Kumagai, S. Kawata and Y. Sakamoto

Abstract: In the title compound, {[Zn(C8H4O4)(C6H6N2O)2]·C6H6N2O}n, the ZnII ion exhibits a tetrahedral coordination environment defined by two benzene-1,4-dicarboxylate dianions and two 4-pyridinealdoxime ligands. The dianions bridge the ZnII ions, giving a zigzag chain along the b axis. Adjacent chains are connected by O-H...O hydrogen bonds, forming a cavity in which an uncoordinating 4-pyridinealdoxime molecule is located; this molecule is linked by O-H...O and O-H...N hydrogen bonds to the zigzag chain.


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