Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m216    [ doi:10.1107/S1600536813006107 ]

catena-Poly[[[bis­(4-pyridine­aldoxime-[kappa]N1)zinc]-[mu]-benzene-1,4-dicarboxyl­ato-[kappa]2O1:O4] 4-pyridine­aldoxime monosolvate]

H. Kumagai, S. Kawata and Y. Sakamoto

Abstract: In the title compound, {[Zn(C8H4O4)(C6H6N2O)2]·C6H6N2O}n, the ZnII ion exhibits a tetra­hedral coordination environment defined by two benzene-1,4-dicarboxylate dianions and two 4-pyridinealdoxime ligands. The dianions bridge the ZnII ions, giving a zigzag chain along the b axis. Adjacent chains are connected by O-H...O hydrogen bonds, forming a cavity in which an uncoordinating 4-pyridine­aldoxime mol­ecule is located; this mol­ecule is linked by O-H...O and O-H...N hydrogen bonds to the zigzag chain.

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