Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)


metal-organic compounds



nc2307 scheme

Acta Cryst. (2013). E69, m211    [ doi:10.1107/S1600536813006879 ]

Dichloridobis(1,3-diisopropyl-4,5-dimethyl-1H-imidazol-3-ium-2-thiolate-[kappa]S)copper(II)

U. Flörke, A. Ahmida, J. Schröder, H. Egold and G. Henkel

Abstract: The molecular structure of the title compound, [CuCl2(C11H20N2S)2], shows the CuII atom with a distorted tetrahedral geometry from two Cl atoms [Cu-Cl = 2.2182 (6) Å] and two thione S atoms [Cu-S = 2.3199 (6) Å]. The angles at the copper cation, which lies on a twofold rotation axis, are Cl-Cu-Cl = 142.84 (4)°, Cl-Cu-S = 94.80 (2) and 99.97 (2)°, and S-Cu-S = 132.46 (4)°. The planes of the two imidazolium rings make a dihedral angle of 76.92 (8)°.


htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813006879/nc2307sup0.html ]
Supplementary materials


Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster