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Acta Cryst. (2013). E69, m200-m201
[ doi:10.1107/S1600536813006521 ]

[1,2-Bis(diisopropylphosphanyl)ethane-[kappa]2P,P'](carbonato-[kappa]2O,O')nickel(II)

I. Morales-Becerril, M. Flores-Alamo and J. J. Garcia

Abstract: In the crystal of the title compound, [Ni(CO3)(C14H32P2)], the metal center in each of three independent molecules shows slight tetrahedral distortion from ideal square-planar coordination geometry, with angles between the normals to the planes defined by the cis-P-Ni-P and cis-O-Ni-O fragments of 3.92 (17), 0.70 (16) and 2.17 (14)° in the three molecules. In the crystal, there are intermolecular C-H...O hydrogen bonds that show a laminar growth in the ab plane.


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