Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m200-m201    [ doi:10.1107/S1600536813006521 ]


I. Morales-Becerril, M. Flores-Alamo and J. J. Garcia

Abstract: In the crystal of the title compound, [Ni(CO3)(C14H32P2)], the metal center in each of three independent mol­ecules shows slight tetra­hedral distortion from ideal square-planar coordination geometry, with angles between the normals to the planes defined by the cis-P-Ni-P and cis-O-Ni-O fragments of 3.92 (17), 0.70 (16) and 2.17 (14)° in the three mol­ecules. In the crystal, there are inter­molecular C-H...O hydrogen bonds that show a laminar growth in the ab plane.

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