Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)


inorganic compounds



Acta Cryst. (2013). E69, i21-i22    [ doi:10.1107/S160053681300771X ]

Ammonium diphosphitoindate(III)

F. Hamchaoui, H. Rebbah and E. Le Fur

Abstract: The crystal structure of the title compound, NH4[In(HPO3)2], is built up from InIII cations (site symmetry 3m.) adopting an octahedral environment and two different phosphite anions (each with site symmetry 3m.) exhibiting a triangular-pyramidal geometry. Each InO6 octahedron shares its six apices with hydrogen phosphite groups. Reciprocally, each HPO3 group shares all its O atoms with three different metal cations, leading to [In(HPO3)2]- layers which propagate in the ab plane. The ammonium cation likewise has site symmetry 3m.. In the structure, the cations are located between the [In(HPO3)2]- layers of the host framework. The sheets are held together by hydrogen bonds formed between the NH4+ cations and the O atoms of the framework.


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