Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)


organic compounds



sj5309 scheme

Acta Cryst. (2013). E69, o621-o622    [ doi:10.1107/S1600536813008222 ]

4-(Decyloxy)phenyl 2-oxo-7-trifluoromethyl-2H-chromene-3-carboxylate

B. S. Palakshamurthy, H. C. Devarajegowda, H. T. Srinivasa, S. Sreenivasa and Vijithkumar

Abstract: The title compound, C27H29F3O5, is a liquid crystal (LC) and exhibits enantiotropic SmA phase transitions. In the crystal, the dihedral angle between the 2H-chromene ring system and the benzene ring is 62.97 (2)°. The three F atoms of the -CF3 group are disordered over two sets of sites with occupancy factors 0.71 (4):0.29 (4). In the crystal, pairs of C-H...O hydrogen bonds form inversion dimers and generate R22(10) rings. The structure also features C-H...F and C-H...[pi] interactions along [100] and [010], respectively.


htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813008222/sj5309sup0.html ]
Supplementary materials


cmldisplay filedownload file

Chemical Markup Language (CML) file (9.3 kbytes)
[ doi:10.1107/S1600536813008222/sj5309Isup3.cml ]
Supplementary material


Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster